Mo(CO)4(2-(phenylazo)pyridine)

Base Information

• Chemical Name: Mo(CO)4(2-(phenylazo)pyridine)
• CAS No.: 118275-51-7
• Molecular Formula: C₁₅H₉MoN₃O₄
• Molecular Weight: 391.194
• Mol file: 118275-51-7.mol

Synonyms:

Chemical Property of Mo(CO)4(2-(phenylazo)pyridine)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Mo(CO)4(2-(phenylazo)pyridine)

There total 1 articles about Mo(CO)4(2-(phenylazo)pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

2-(phenylazo)pyridine (2569-57-5) + (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) → Mo(CO)4(2-(phenylazo)pyridine) (118275-51-7)

Guidance literature:

In hexane; under dry and oxygen-free atmosphere of N2, equimolar amounts of C7H8Mo(CO)4 and 2-(phenylazo)pyridine, dissolved (hexane), stirred, infrared monitoring (CO stretching), 17 h reaction time; filtered, washed (hexane), filtrate and washings combined, cooled, -78°C, cold filtered, washed (cold hexane), dried (vac.); elem. anal.;

Reference yield: 35.0%

Mo(CO)4(2-(phenylazo)pyridine) (118275-51-7) → fac-Mo(CO)3(PPh3)(2-(phenylazo)pyridine) (118275-59-5)

Guidance literature:

With triphenyl phosphine; In hexane; under dry and oxygen-free atmosphere of N2, Mo(CO)4(C11H9N3) and PPh3 (1:2), n-hexane, refluxed, 24 h, cooled; filtered, washed (petroleum ether), chromy. (Florisil, CH2Cl2/petroleum ether 1:1), crystn. (CH2Cl2/hexane); elem. anal.;

upstream raw materials:

2-(phenylazo)pyridine

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾

Downstream raw materials:

fac-Mo(CO)3(PPh₃)(2-(phenylazo)pyridine)

Refernces