C₃₇H₃₈Cl₆O₁₆

Base Information

• Chemical Name: C₃₇H₃₈Cl₆O₁₆
• CAS No.: 110259-03-5
• Molecular Formula: C₃₇H₃₈Cl₆O₁₆
• Molecular Weight: 951.417
• Mol file: 110259-03-5.mol

Synonyms:

Chemical Property of C₃₇H₃₈Cl₆O₁₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₇H₃₈Cl₆O₁₆

There total 4 articles about C₃₇H₃₈Cl₆O₁₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C44H46Cl6O17 (95603-47-7,95672-97-2) → C37H38Cl6O16 (110259-03-5)

Guidance literature:

With lead(IV) acetate; In acetic acid; for 0.5h; Ambient temperature;

DOI:10.1016/S0040-4020(01)87285-9

Reference yield:

10-deacetylbaccatin III (32981-86-5,172018-16-5) → C37H38Cl6O16 (110259-03-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 153 mg / pyridine / 0.08 h / 80 °C

2: 42 mg / 1.) oxalyl chloride; 2.) silver cyanide / toluene / 20 h / 110 °C

3: 115 mg / osmium tetroxide / pyridine / 1 h / Ambient temperature

4: 309 mg / lead tetraacetate / acetic acid / 0.5 h / Ambient temperature

With lead(IV) acetate; osmium(VIII) oxide; silver cyanide; oxalyl dichloride; In pyridine; acetic acid; toluene;

DOI:10.1016/S0040-4020(01)87285-9

Reference yield:

7,10-di(2,2,2-trichloroethyloxy-carbonyl)-13-cinnamoyl-10-deacetyl baccatin III (95603-45-5,110281-75-9) → C37H38Cl6O16 (110259-03-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 115 mg / osmium tetroxide / pyridine / 1 h / Ambient temperature

2: 309 mg / lead tetraacetate / acetic acid / 0.5 h / Ambient temperature

With lead(IV) acetate; osmium(VIII) oxide; In pyridine; acetic acid;

DOI:10.1016/S0040-4020(01)87285-9

upstream raw materials:

C₄₄H₄₆Cl₆O₁₇

10-deacetylbaccatin III

7,10-di(2,2,2-trichloroethyloxy-carbonyl)-13-cinnamoyl-10-deacetyl baccatin III

7,10-di-(2,2,2-trichloroethyloxycarbonyl)-10-deacetylbaccatin III

Downstream raw materials:

13-hydroxy acetyl-10-deacetyl baccatin III

Refernces