IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2

Base Information

• Chemical Name: IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2
• CAS No.: 87482-56-2
• Molecular Formula: C₅₃H₄₄ClIrO₃P₄Rh
• Molecular Weight: 1183.4
• Mol file: 87482-56-2.mol

Synonyms:

Chemical Property of IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2

There total 1 articles about IrRhCl(CO)3(((C₆H₅)2P)2CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di(rhodium)tetracarbonyl dichloride + [Ir(CO)(bis(diphenylphosphino)methane)2][Cl] (15024-82-5) → IrRh(CO)2Cl(CH2(P(C6H5)2)2)2(1+) (87482-57-3) + IrRh(CO)3Cl(CH2(P(C6H5)2)2)2(1+)*Cl(1-)*CH2Cl2 = IrRh(CO)3Cl(CH2(P(C6H5)2)2)2Cl*CH2Cl2 (87482-56-2)

Guidance literature:

In dichloromethane; 20°C; elem. anal.;

Reference yield:

IrRhCl(CO)3(((C6H5)2P)2CH2)2 (87482-56-2) + propynoic acid methyl ester (922-67-8) → IrCl(CO)RhCl(CF3C2CF3)(((C6H5)2P)2CH2)2*1.5CHCl3 (100857-91-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; dichloromethane; pressurizing complex in CO-satd. solvent with ligand and CO, stirring for 0.5 h, filtering through diatomaceous earth, addn. of Et2O, filteringoff, refluxing of the solid in THF under N2 purge for 5 h; filtn. through diatomaceous earth, addn. of Et2O, filtn., recrystallization from CHCl3-Et2O; elem. anal.;

DOI:10.1021/om00136a014

Reference yield:

IrRhCl(CO)3(((C6H5)2P)2CH2)2 (87482-56-2) + dimethyl acetylenedicarboxylate (762-42-5) → IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2 (100896-61-5) + IrCl(CO)RhCl(CO)(CH3OCOC2CO2CH3)(((C6H5)2P)2CH2)2*0.5CH2Cl2 (100815-11-0)

Guidance literature:

With carbon monoxide; In dichloromethane; excess of ligand was added to complex in CO-satd. CH2Cl2, mixt. was stirred for 1 h under CO; filtn. through diatomaceous earth, addn. of hexane, filtn., recrystallization from CH2Cl2-Et2O; elem. anal.; presence of other isomer is confirmed by IR and NMR;

DOI:10.1021/om00136a014

upstream raw materials:

[Ir(CO)(bis(diphenylphosphino)methane)2][Cl]

Downstream raw materials:

IrCl(CO)RhCl(CF₃C₂CF₃)(((C₆H₅)2P)2CH₂)2*1.5CHCl₃

IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2

IrCl(CO)RhCl(CO)(CH₃OCOC₂CO₂CH₃)(((C₆H₅)2P)2CH₂)2*0.5CH₂Cl₂

Refernces