Phosphoric acid vinyldimethyl ester

Base Information

• Chemical Name: Phosphoric acid vinyldimethyl ester
• CAS No.: 10429-10-4
• Molecular Formula: C4H9O4P
• Molecular Weight: 152.087
• Hs Code.: 2919900090
• Mol file: 10429-10-4.mol

Synonyms:Dimethyl vinyl phosphate;Vinyldimethylphosphat;Dimethylvinylphosphat;Phosphoric acid,dimethyl vinyl ester;phosphoric acid dimethyl ester vinyl ester;Phosphoric acid,ethenyl dimethyl ester;

Chemical Property of Phosphoric acid vinyldimethyl ester

Chemical Property:

• PSA: 54.57000
• LogP: 1.54740

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dimethylvinylphosphate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphoric acid vinyldimethyl ester

There total 3 articles about Phosphoric acid vinyldimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + Dimethyl chlorophosphate (813-77-4) → phosphoric acid dimethyl ester vinyl ester (10429-10-4)

Guidance literature:

tetrahydrofuran; With n-butyllithium; In hexane; at 0 - 25 ℃; for 18.5h;

Dimethyl chlorophosphate; at -78 - 20 ℃; for 0.75h;

DOI:10.1021/jo0513562

Reference yield:

2-chloroethanal (107-20-0) + phosphorous acid trimethyl ester (121-45-9) → phosphoric acid dimethyl ester vinyl ester (10429-10-4)

Guidance literature:

In benzene;

Reference yield:

→ phosphoric acid dimethyl ester vinyl ester (10429-10-4)

Guidance literature:

Monochloraethylencarbonat, Trimethylphosphit;

DOI:10.1021/jo01281a086

upstream raw materials:

2-chloroethanal

phosphorous acid trimethyl ester

tetrahydrofuran

Dimethyl chlorophosphate

Downstream raw materials:

trimethyl phosphite

bromoacetaldehyde

Refernces

• 1、 Kumpulainen, Hanna,Jaervinen, Tomi,Saari, Raimo,Lehtonen, Marko,Vepsaelaeinen, Jouko. "An efficient strategy for the synthesis of 1-chloroethyl phosphates and phosphoramidates". . p. 9056 - 9058. Retrieved 2007/10/03.