cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)

Base Information

• Chemical Name: cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)
• CAS No.: 143672-23-5
• Molecular Formula: C₂₆H₂₈Cl₂InN₅
• Molecular Weight: 596.268
• Mol file: 143672-23-5.mol

Synonyms:

Chemical Property of cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III)

There total 2 articles about cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3,5-Lutidine (591-22-0) + triethylammonium cis-dichlorobis(1,3-diphenyltriazenido)indate(III) → cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III) (143672-23-5)

Guidance literature:

In acetonitrile; byproducts: C6H5NHNNC6H5; addn. of pyridine via syringe to In complex soln. under N2; immediate pptn.; stirring suspension, 1h; evapn.; washing (pentane); drying (vac.); crystn. (CH2Cl2 layered with pentane, -24°C); elem. anal.;

DOI:10.1039/DT9920002183

Reference yield: 90.0%

3,5-Lutidine (591-22-0) + tetraethylammonium cis-dichlorobis(1,3-diphenyltriazenido)indate(III) → cis-dichloro-trans-bis(3,5-dimethylpyridine)(1,3-diphenyltriazenido)indium(III) (143672-23-5)

Guidance literature:

With CF₃CO₂H; In not given; byproducts: {N(C2H5)4}{O2CCF3}, PhNHNNPh;

DOI:10.1039/DT9920002183

upstream raw materials:

3,5-Lutidine

Refernces