N-Cyclohexylcyclohexylideneamine

Base Information

• Chemical Name: N-Cyclohexylcyclohexylideneamine
• CAS No.: 10468-40-3
• Molecular Formula: C12H21N
• Molecular Weight: 179.305
• Hs Code.: 2921300090
• Mol file: 10468-40-3.mol

Synonyms:N-cyclohexyl-N-cyclohexylidenamine;N-cyclohexyl-cyclohexylidene amine;N-cyclohexylidenecyclohexanamine;N-cyclohexylidenecyclohexylamine;(cyclohexylidene)cyclohexylamine;

Chemical Property of N-Cyclohexylcyclohexylideneamine

Chemical Property:

• Melting Point: 23-24 °C
• Boiling Point: 117-118 °C(Press: 9 Torr)
• PKA: 7.66±0.20(Predicted)
• PSA: 12.36000
• Density: 0.940 g/cm3(Temp: 21 °C)
• LogP: 3.72420

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Cyclohexylcyclohexylideneamine

There total 58 articles about N-Cyclohexylcyclohexylideneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

cyclohexylamine (108-91-8,157973-60-9) + cyclohexanol (108-93-0) → cyclohexanone N-cyclohexylimine (10468-40-3) + N-cyclohexyl-cyclohexanamine (101-83-7)

Guidance literature:

With Mg-Al hydrotalcite supported copper; at 180 ℃; for 15h;

DOI:10.1016/j.catcom.2012.12.027

Reference yield:

cyclohexylamine (108-91-8,157973-60-9) → N-phenyl-2-cyclohexylamine (1821-36-9) + cyclohexanone N-cyclohexylimine (10468-40-3) + diphenylamine (122-39-4) + aniline (62-53-3) + N-cyclohexyl-cyclohexanamine (101-83-7)

Guidance literature:

chromium; silica gel; nickel; copper; sodium sulfate; at 390 ℃; Product distribution; Mechanism; other volume flow rate;

Reference yield:

cyclohexylamine (108-91-8,157973-60-9) → N-phenyl-2-cyclohexylamine (1821-36-9) + cyclohexanone N-cyclohexylimine (10468-40-3)

Guidance literature:

With 7.8 mol%Au-1 mol%Pd/Al2O3; In 1,3,5-trimethyl-benzene; at 130 ℃; for 3h; under 760.051 Torr; chemoselective reaction;

DOI:10.1039/c5cc06514c

upstream raw materials:

cyclohexanone-oxime

cyclohexanone

cyclohexylamine

sodium cyanide

Downstream raw materials:

1-(benzoyl-cyclohexyl-amino)-cyclohexanecarbonitrile

2-acetylcyclohexanone

3,3'-(2-cyclohexylimino-cyclohexane-1,3-diyl)-di-propionitrile

3-(2-cyclohexylimino-cyclohexyl)-propionitrile

Refernces

• 1、 Naya, Shin-Ichi,Warita, Masato,Mitsumoto, Yuhki,Nitta, Makoto. "New synthesis, properties, and oxidizing ability of 1,3-dimethyl-5,10- methanocycloundeca[4,5]furo[2,3-d]pyrimidin-2,4(1,3H)-dionylium tetrafluoroborate". . p. 9184 - 9190. Retrieved 2004.
• 2、 Curton, Nicholas,Ornelas, Joel,Uhrinak, Abby,Rhem, Brittney,Coulter, Jess,Zhang, Joe,Joyner, P. Matthew,White, James B.. "Synthesis of 5-cyclodecenones via RCM and a three-pot sequence for bisannulation". . p. 4061 - 4065. Retrieved 2016.
• 3、 Taniguchi, Kento,Jin, Xiongjie,Yamaguchi, Kazuya,Mizuno, Noritaka. "Supported gold-palladium alloy nanoparticle catalyzed tandem oxidation routes to N-substituted anilines from non-aromatic compounds". . p. 14969 - 14972. Retrieved 2015.
• 4、 Zhang, Chenghui,Zhao, Pengshan,Zhang, Zongliang,Zhang, Jingwei,Yang, Ping,Gao, Peng,Gao, Jun,Liu, Di. "Co-N-C supported on SiO2: A facile, efficient catalyst for aerobic oxidation of amines to imines". . p. 47366 - 47372. Retrieved 2017.
• 5、 Liu, Lianghui,Wang, Zikuan,Fu, Xuefeng,Yan, Chun-Hua. "Azobisisobutyronitrile initiated aerobic oxidative transformation of amines: Coupling of primary amines and cyanation of tertiary amines". . p. 5692 - 5695. Retrieved 2012.
• 6、 Wehrmeister. "-". . p. 2132,2133. Retrieved 1960.
• 7、 Li, Xin-Hao,Antonietti, Markus. "Polycondensation of boron- and nitrogen-codoped holey graphene monoliths from molecules: Carbocatalysts for selective oxidation". . p. 4572 - 4576. Retrieved 2013.
• 8、 Ratcliff,Kochi. "-". . p. 4467,4477,4480. Retrieved 1972.
• 9、 -. "Preparation method of cyclohexanone oxime". Paragraph 0072-0073. . Retrieved 2021/06/13.
• 10、 Pietrobon, L.,Pontello, R.,Ronchin, L.,Sadraoui, C.,Tosetto, C.,Vavasori, A.. "Pd/C Catalyzed selective hydrogenation of nitrobenzene to cyclohexanone oxime in the presence of NH2OH·HCl: Influence of the operative variables and insights on the reaction mechanism". . . Retrieved 2020/05/05.