[(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)]

Base Information

• Chemical Name: [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)]
• CAS No.: 508193-68-8
• Molecular Formula: C₄₃H₃₆Co₂O₄P₂
• Molecular Weight: 796.69
• Mol file: 508193-68-8.mol

Synonyms:

Chemical Property of [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)]

There total 3 articles about [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(4-(hydroxylcyclopentylyl)buta-1,3-diynyl)cyclopentanol (7179-09-1) → [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)] (508193-68-8)

Guidance literature:

Multi-step reaction with 3 steps

1: diethyl ether

2: tetrafluoroboric acid / dichloromethane

3: toluene

tetrafluoroboric acid; In diethyl ether; dichloromethane; toluene;

DOI:10.1039/b206295j

Reference yield:

[(dicobalt hexacarbonyl)-(μ-η2-C5H8OHCCCCC5H8OH)] (508193-62-2) → [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)] (508193-68-8)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrafluoroboric acid / dichloromethane

2: toluene

tetrafluoroboric acid; In dichloromethane; toluene;

DOI:10.1039/b206295j

Reference yield:

[(dicobalt hexacarbonyl)-(μ-η2-C5H7CCCCC5H7)] (508193-66-6) → [(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CCCCC5H7)] (508193-68-8) + [[(dicobalt tetracarbonyl)(bis(diphenylphosphino)methane)(μ-η2-C5H7CC)]2]

Guidance literature:

In toluene; byproducts: CO; to a soln. of the complex in toluene added bis(diphenylphosphino)methane, mixture heated to 70 °C for one hour; silica-gel column chromy. (hexane:dichloromethane 4:1 v/v) afforded two fractions, the first and major fraction mono(dicobalt tetracarbonyl)-coordinated complex and the minor second fraction the bis(dicobalt tetracarbonyl)-coordinated complex;

DOI:10.1039/b206295j

upstream raw materials:

[(dicobalt hexacarbonyl)-(μ-η2-C5H7CCCCC5H7)]

1-(4-(hydroxylcyclopentylyl)buta-1,3-diynyl)cyclopentanol

[(dicobalt hexacarbonyl)-(μ-η2-C5H8OHCCCCC5H8OH)]

Refernces