[Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2]

Base Information

• Chemical Name: [Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2]
• CAS No.: 1207107-24-1
• Molecular Formula: C₆₈H₆₄Cl₂N₄P₂Ru
• Molecular Weight: 1171.21
• Mol file: 1207107-24-1.mol

Synonyms:

Chemical Property of [Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2]

There total 1 articles about [Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + 1-Methylbenzimidazole (1632-83-3) + (R)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl (135139-00-3,137219-86-4,145416-77-9) → [Cl2Ru((R)-2,2'-bis(3,5-xylylphosphino)-1,1'-binaphthyl)(κN3-1-methylbenzimidazole)2] (1207107-24-1)

Guidance literature:

In N,N-dimethyl-formamide; (N2); addn. of (RuCl2(C6H6))2 and (R)-XylBINAP to Schlenk flask with stirrer; dissolving in DMF; heating to 100°C; degassing; cooling to 35°C; removal of volatiles (vac.) overnight; dissolving in THF; addn. of MeC7H5N2; stirring for 16 h; concn. on vac.; filtration, concn.; layring with hexanes; recrystn. at -20°C; filtration, elem. anal.;

DOI:10.1021/om900897b

upstream raw materials:

dichloro(benzene)ruthenium(II) dimer

1-Methylbenzimidazole

(R)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl

Refernces