[(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3

Base Information

• Chemical Name: [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3
• CAS No.: 1338052-05-3
• Molecular Formula: C₁₇H₁₃CrNO₄
• Molecular Weight: 347.291
• Mol file: 1338052-05-3.mol

Synonyms:

Chemical Property of [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3

There total 2 articles about [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

2-acetamidobiphenyl (2113-47-5) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (CH3CONHC6H4C6H5)Cr(CO)3 (1338052-05-3) + [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3 (1338052-05-3)

Guidance literature:

In tetrahydrofuran; dibutyl ether; (N2) mixt. Cr(CO)6 and 2-acetamidobiphenyl in n-Bu2O-THF was heated under reflux for 24 h; solvents were removed in vacuo, column chromy. on silica (hexane-Et2O 25:75); elem. anal.;

DOI:10.1039/c1dt10994d

Reference yield: 38.0%

2-acetamidobiphenyl (2113-47-5) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (CH3CONHC6H4C6H5)Cr(CO)3 (1338052-05-3) + [(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3 (1338052-05-3)

Guidance literature:

In tetrahydrofuran; dibutyl ether; (N2) mixt. Cr(CO)6 and 2-acetamidobiphenyl in n-Bu2O-THF was heated under reflux for 24 h; solvents were removed in vacuo, column chromy. on silica (hexane-Et2O 25:75); elem. anal.;

DOI:10.1039/c1dt10994d

Reference yield: 37.0%

[(η6-C6H5)(C6H4-2-NHCOCH3)]Cr(CO)3 (1338052-05-3) → [(η6-C6H5)(C6H4-2-NH2)]Cr(CO)3

Guidance literature:

With potassium hydroxide; In ethanol; water; (N2) mixt. Cr complex and KOH in aq. EtOH was heated at 80°C for 7 h; soln. was extd. with CH2Cl2, dried over MgSO4, filtered, concd. and chromd. on silica (hexane-Et2O 50:50); elem. anal.;

DOI:10.1039/c1dt10994d

upstream raw materials:

2-acetamidobiphenyl

chromium⁽⁰⁾ hexacarbonyl

Refernces