(C₆H₅)2(CH₂CO(C₆H₅))PFe(CO)4

Base Information

• Chemical Name: (C₆H₅)2(CH₂CO(C₆H₅))PFe(CO)4
• CAS No.: 83292-54-0
• Molecular Formula: C₂₄H₁₇FeO₅P
• Molecular Weight: 472.217
• Mol file: 83292-54-0.mol

Synonyms:

Chemical Property of (C₆H₅)2(CH₂CO(C₆H₅))PFe(CO)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)2(CH₂CO(C₆H₅))PFe(CO)4

There total 2 articles about (C₆H₅)2(CH₂CO(C₆H₅))PFe(CO)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + Phenacyldiphenylthiophosphoran (58156-55-1) → (C6H5)2(CH2CO(C6H5))PFe(CO)4 (83292-54-0)

Guidance literature:

In toluene; heated at 80°C for 3 h, then at 130°C for 1 h; filtration, concn., column chromy. (silica gel, hexane/toluene 80/20);

DOI:10.1016/S0022-328X(00)92891-2

Reference yield: 53.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + (diphenylphosphino)acetophenone (82363-89-1) → Fe(CO)4((C6H5)2PCH2C(O)C6H5) (83292-54-0)

Guidance literature:

With (CH₃)3NO; In tetrahydrofuran; P-comp. was added to a THF soln. of Fe-comp. at -78 °C. Me3NO was added over a period of 15 min. The reaction mixture was then slowly brought to room temp. (2h).; Solvent was evaporated under reduced pressure, the residue chromatographed on alumina. Elution with CH2Cl2/pentane (1:3) gave the Fe-complex, which was recrystallized from CH2Cl2/hexane. Elem. anal.;

Reference yield: 87.0%

(C6H5)2(CH2CO(C6H5))PFe(CO)4 (83292-54-0) + copper dichloride → ((C6H5)2P(CH2COC6H5))2Fe(CO)2Cl2 (83293-22-5)

Guidance literature:

In methanol; stirred for 15 min, Ar atm.; evapn., extn. (methylene chloride), filtration, evapn.;

DOI:10.1016/S0022-328X(00)92891-2

upstream raw materials:

iron pentacarbonyl

(diphenylphosphino)acetophenone

Phenacyldiphenylthiophosphoran

Downstream raw materials:

((C₆H₅)2P(CH₂COC₆H₅))2Fe(CO)2Cl₂

Refernces

• 1、 Mercier, Francois,Mathey, Francois,Angenault, Jacques,Couturier, Jean-Claude,Mary, Yves. "LA REDUCTION-COMPLEXATION DES SULFURES DE PHOSPHINES PAR LE FER PENTACARBONYLE: UN OUTIL ORIGINAL POUR LA SYNTHESE DES PHOSPHINES". . p. 237 - 244. Retrieved 2007/10/02.