((C₆H₅)3P)AuCCC(CH₃)2OH

Base Information

• Chemical Name: ((C₆H₅)3P)AuCCC(CH₃)2OH
• CAS No.: 1349835-59-1
• Molecular Formula: C₂₃H₂₂AuOP
• Molecular Weight: 542.367
• Mol file: 1349835-59-1.mol

Synonyms:

Chemical Property of ((C₆H₅)3P)AuCCC(CH₃)2OH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((C₆H₅)3P)AuCCC(CH₃)2OH

There total 2 articles about ((C₆H₅)3P)AuCCC(CH₃)2OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

acetato(triphenylphosphine)gold(I) (24169-88-8) + 2-methyl-but-3-yn-2-ol (115-19-5) → ((C6H5)3P)AuCCC(CH3)2OH (1349835-59-1)

Guidance literature:

In [D₃]acetonitrile; at 20 ℃; for 0.0166667h;

DOI:10.1021/ja5078365

Reference yield: 59.3%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 2-methyl-but-3-yn-2-ol (115-19-5) → ((C6H5)3P)AuCCC(CH3)2OH (1349835-59-1)

Guidance literature:

With sodium hydroxide; In methanol; dichloromethane; (N2) react. Au complex, alkyne and NaOH in CH2Cl2-MeOH was stirred overnight; volatiles were removed in vacuo, residue was extd. with benzene and filtered, recrystn. by pentane diffusion into benzene-CH2Cl2 soln.; elem. anal.;

DOI:10.1039/c1dt11337b

Reference yield: 75.0%

((C6H5)3P)AuCCC(CH3)2OH (1349835-59-1) + phosphonic acid diethyl ester (762-04-9) → Ph3PAu(P(O)(OEt)2)

Guidance literature:

In benzene-d6; 64°C; soln. was concd. in vacuo, residue was triturated with Et2O-hexane (2:1)and dried in vacuo; elem. anal.;

DOI:10.1039/c1dt11337b

upstream raw materials:

(triphenylphosphine)gold(I) chloride

2-methyl-but-3-yn-2-ol

acetato(triphenylphosphine)gold(I)

Refernces

• 1、 Manbeck, Gerald F.,Kohler, Mark C.,Porter, Meghan R.,Stockland Jr., Robert A.. "P-H activation using alkynylgold substrates: Steric and electronic effects". . p. 12595 - 12606. Retrieved 2012/01/04.