1-methoxycaryolane

Base Information

• Chemical Name: 1-methoxycaryolane
• CAS No.: 86377-29-9
• Molecular Formula: C₁₆H₂₈O
• Molecular Weight: 236.398
• Mol file: 86377-29-9.mol

Synonyms:

Chemical Property of 1-methoxycaryolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-methoxycaryolane

There total 1 articles about 1-methoxycaryolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + caryolane chloride (97673-50-2) → β-caryolanol (58404-89-0,82008-48-8,129445-45-0,472-97-9) + 11β-methoxy-3,3,7β-trimethyl-1β,4β-tricyclo<5.3.2.04,11>dodecane (86377-32-4,97673-53-5) + 1-methoxycaryolane (86377-29-9,97673-51-3)

Guidance literature:

Yield given. Multistep reaction; 1) SbF₅-SO₂FCl, -120 deg C, 2) diethyl ether, -100 deg C;

Reference yield:

1-methoxycaryolane (86377-29-9,97673-51-3) → β-caryolanol (58404-89-0,82008-48-8,129445-45-0,472-97-9)

Guidance literature:

With fluorosulfonylchloride; water; antimony pentafluoride; at -120 ℃;

Reference yield:

1-methoxycaryolane (86377-29-9,97673-51-3) → β-caryolanol (58404-89-0,82008-48-8,129445-45-0,472-97-9) + 3,3,7β-trimethyl-1β,4β-tricyclo<5.3.2.04,11>dodecan-11β-ol (86377-31-3,97673-54-6)

Guidance literature:

With fluorosulfonylchloride; water; antimony pentafluoride; 1) -120 deg C, 2) acetone, -100 deg C;

upstream raw materials:

methanol

caryolane chloride

Downstream raw materials:

β-caryolanol

3,3,7β-trimethyl-1β,4β-tricyclo<5.3.2.0^4,11>dodecan-11β-ol

Refernces