Technology Process of (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane
There total 11 articles about (+/-)-3-oximino-1,4,4-trimethylbicyclo<3.2.0>heptane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 90 percent / Amberlist A-15 / H2O; acetone / 24 h / Ambient temperature
2: trimethylsylilmethylmagnesium chloride / 20 h / Ambient temperature
3: 90 percent / coprous trifluormethanesulphonate-benzene complex / diethyl ether / 65 h / Irradiation
4: 94 percent / pyridinium chlorochromate / Celite / CH2Cl2 / 4 h / Ambient temperature
5: 80 percent / hydroxylamine hydrochloride, potassium carbonate / ethanol / 3 h / Heating
With
copper(I) trifluoromethanesulfonate benzene; trimethylsylilmethylmagnesium chloride; hydroxylamine hydrochloride; potassium carbonate; pyridinium chlorochromate;
Amberlist A-15; Celite;
In
diethyl ether; ethanol; dichloromethane; water; acetone;
DOI:10.1016/S0040-4020(01)96088-0
- Guidance literature:
-
Multi-step reaction with 4 steps
1: trimethylsylilmethylmagnesium chloride / 20 h / Ambient temperature
2: 90 percent / coprous trifluormethanesulphonate-benzene complex / diethyl ether / 65 h / Irradiation
3: 94 percent / pyridinium chlorochromate / Celite / CH2Cl2 / 4 h / Ambient temperature
4: 80 percent / hydroxylamine hydrochloride, potassium carbonate / ethanol / 3 h / Heating
With
copper(I) trifluoromethanesulfonate benzene; trimethylsylilmethylmagnesium chloride; hydroxylamine hydrochloride; potassium carbonate; pyridinium chlorochromate;
Celite;
In
diethyl ether; ethanol; dichloromethane;
DOI:10.1016/S0040-4020(01)96088-0