CpRu(P(p-CF₃C₆H₄)3)2(CN)

Base Information

• Chemical Name: CpRu(P(p-CF₃C₆H₄)3)2(CN)
• CAS No.: 204455-57-2
• Molecular Formula: C₄₈H₂₉F₁₈NP₂Ru
• Molecular Weight: 1124.75
• Mol file: 204455-57-2.mol

Synonyms:

Chemical Property of CpRu(P(p-CF₃C₆H₄)3)2(CN)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CpRu(P(p-CF₃C₆H₄)3)2(CN)

There total 2 articles about CpRu(P(p-CF₃C₆H₄)3)2(CN) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[CpRu(P(p-CF3C6H4)3)2CNH(+)]CF3SO3(-) (204455-82-3) → CpRu(P(p-CF3C6H4)3)2(CN) (204455-57-2)

Guidance literature:

With diphenylguanidine; In not given; byproducts: diphenylguanidinium triflate; inert atmosphere; equimolar amts.; chromy. (Al2O3, CH2Cl2);

DOI:10.1021/ic971124o

Reference yield:

sodium cyanide (773837-37-9) + (η(5)-C5H5)RuCl(P(p-CF3C6H4)3)2 (172220-60-9) → CpRu(P(p-CF3C6H4)3)2(CN) (204455-57-2)

Guidance literature:

In methanol; byproducts: NaCl; inert atmosphere; excess NaCN, stirring and refluxing;

DOI:10.1021/ic971124o

Reference yield:

CpRu(P(p-CF3C6H4)3)2(CN) (204455-57-2) + trifluorormethanesulfonic acid (1493-13-6) → [CpRu(P(p-CF3C6H4)3)2CNH(+)]CF3SO3(-) (204455-82-3)

Guidance literature:

In dichloromethane-d2; N2-atmosphere; addn. of 1 equiv. TfOH to metal complex; not isolated, detd. by NMR spectroscopy;

DOI:10.1021/ic971124o

upstream raw materials:

sodium cyanide

(η(5)-C5H5)RuCl(P(p-CF3C6H4)3)2

[CpRu(P(p-CF₃C₆H₄)3)2CNH(+)]CF₃SO₃(-)

Downstream raw materials:

[CpRu(P(p-CF₃C₆H₄)3)2CNH(+)]CF₃SO₃(-)

Refernces