β-dihydrolycopodine

Base Information

• Chemical Name: β-dihydrolycopodine
• CAS No.: 23768-74-3
• Molecular Formula: C₁₆H₂₇NO
• Molecular Weight: 249.396
• Mol file: 23768-74-3.mol

Synonyms:

Chemical Property of β-dihydrolycopodine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-dihydrolycopodine

There total 1 articles about β-dihydrolycopodine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

C16H23NO2 → lycopodine (466-61-5) + β-dihydrolycopodine (23768-74-3)

Guidance literature:

C₁₆H₂₃NO₂; With lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; at 60 ℃; for 6h; Inert atmosphere;

With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; at -78 - 20 ℃; for 7h; enantioselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.6b02072

Reference yield: 67.0%

β-dihydrolycopodine (23768-74-3) → lycopodine (466-61-5)

Guidance literature:

With Jones reagent; In acetone; at 0 ℃; enantioselective reaction;

DOI:10.1021/acs.orglett.6b02072

Downstream raw materials:

lycopodine

Refernces