[Fe3(μ3-PhAs)2(CO)9]

Base Information

• Chemical Name: [Fe3(μ3-PhAs)2(CO)9]
• CAS No.: 62369-56-6
• Molecular Formula: C₂₁H₁₀As₂Fe₃O₉
• Molecular Weight: 723.689
• Mol file: 62369-56-6.mol

Synonyms:

Chemical Property of [Fe3(μ3-PhAs)2(CO)9]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe3(μ3-PhAs)2(CO)9]

There total 2 articles about [Fe3(μ3-PhAs)2(CO)9] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

triiron dodecarbonyl (17685-52-8) + hexaphenylcyclohexaarsane (20738-31-2) → [Fe3(μ3-PhAs)2(CO)9] (62369-56-6)

Guidance literature:

In toluene; Fe-complex was added to soln. of ligand in toluene, heated to 90°C for 5 h, cooled to room temp. under N2; solvent was removed under reduced pressure, redissolved in CH2Cl2, silica was added, pumped dry, silica chromy. column eluted with hexane-CH2Cl2; elem. anal.;

DOI:10.1016/S0022-328X(02)01892-2

Reference yield:

triiron dodecarbonyl (17685-52-8) + hexaphenylcyclohexaphosphane (4552-71-0) + hexaphenylcyclohexaarsane (20738-31-2) → Bis(μ3-Phenyl-phosphiniden)-tris(tricarbonyleisen)(2Fe-Fe) + [Fe3(μ3-PhAs)2(CO)9] (62369-56-6) + [Fe3(μ3-PhP)(μ3-AsPh)(CO)9]

Guidance literature:

In toluene; High Pressure; Fe-complex and ligands were dissolved in toluene, evacuated, sealed under reduced pressure, stirred at 90°C for 24 h, cooled; filtered, solvent was removed under reduced pressure, dissolved in CH2Cl2, TLC, eluted with hexane-CH2Cl2;

DOI:10.1016/S0022-328X(02)01892-2

Reference yield: 63.0%

[Fe3(μ3-PhAs)2(CO)9] (62369-56-6) + diphenyl acetylene (501-65-5) → ((C6H5)AsC(C6H5)C(C6H5)As(C6H5))((C6H5)CC(C6H5))Fe3(CO)7 + ((C6H5)AsC(C6H5)C(C6H5)As(C6H5))Fe3(CO)9

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); under inert gas, irradiated (Hg lamp, 10°C, 4 h); volume reduced; chromd. (-25°C, silica gel, n-pentane/CH2Cl2); recrystd. (n-pentane/toluene); elem. anal.;

DOI:10.1016/0022-328X(86)80477-6

upstream raw materials:

triiron dodecarbonyl

hexaphenylcyclohexaarsane

hexaphenylcyclohexaphosphane

Refernces