4'-methoxy-1-N-methylaminoazobenzene

Base Information

• Chemical Name: 4'-methoxy-1-N-methylaminoazobenzene
• CAS No.: 21924-71-0
• Molecular Formula: C₁₄H₁₅N₃O
• Molecular Weight: 241.293
• Mol file: 21924-71-0.mol

Synonyms:

Chemical Property of 4'-methoxy-1-N-methylaminoazobenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-methoxy-1-N-methylaminoazobenzene

There total 5 articles about 4'-methoxy-1-N-methylaminoazobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4-methoxybenzenediazonium tetrafluoroborate (459-64-3) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → 4'-methoxy-1-N-methylaminoazobenzene (21924-71-0) + 1-(4-methoxyphenyl)-3-phenyl-3-methyltriazene (28149-16-8)

Guidance literature:

With triethylamine hydrochloride; In butanone; Rate constant; Product distribution; effect of reagent concentration, solvent;

Reference yield: 61.0%

4-methoxybenzenediazonium tetrafluoroborate (459-64-3) + N-methylaniline (100-61-8) → 4'-methoxy-1-N-methylaminoazobenzene (21924-71-0) + 1-(4-methoxyphenyl)-3-phenyl-3-methyltriazene (28149-16-8)

Guidance literature:

With tetrabutyl-ammonium chloride; In acetonitrile;

Reference yield: 32.0%

4-(4-methoxyphenylazo)-N,N-dimethylaniline N-oxide (108178-66-1) → 4'-methoxy-1-N-methylaminoazobenzene (21924-71-0) + N-[4-(4-Methoxy-phenylazo)-phenyl]-N-methyl-formamide (99686-19-8) + 4-(4-methoxyphenylazo)-N,N-dimethylaniline (3009-50-5)

Guidance literature:

In benzene; at 17 ℃; for 6h; Irradiation;

upstream raw materials:

4-methoxybenzenediazonium tetrafluoroborate

N,N-dimethyl-aniline

4-(4-methoxyphenylazo)-N,N-dimethylaniline N-oxide

1-(4-methoxyphenyl)-3-phenyl-3-methyltriazene

Refernces

• 1、 Albini, Angelo,Fasani, Elisa,Moroni, Micaela,Pietra, Silvio. "Photochemical Decomposition of 4-Arylazo- and 4-Arylazoxy-N,N-dialkylaniline N-Oxides". . p. 1439 - 1444. Retrieved 2007/10/02.