Technology Process of (2-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)trimethylstannane
There total 4 articles about (2-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)trimethylstannane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tert.-butylnitrite; toluene-4-sulfonic acid;
In
1,2-dichloro-ethane;
at 0 ℃;
for 4h;
Inert atmosphere;
DOI:10.1021/jo402618r
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 2-(4-biphenylyl)-5-phenyloxazole; tert.-butylnitrite / acetonitrile / 4 h / 20 °C
2: 5%-palladium/activated carbon; hydrogen / methanol / 4 h / 20 °C / 760.05 Torr
3: tert.-butylnitrite; toluene-4-sulfonic acid / 1,2-dichloro-ethane / 4 h / 0 °C / Inert atmosphere
With
tert.-butylnitrite; 5%-palladium/activated carbon; 2-(4-biphenylyl)-5-phenyloxazole; hydrogen; toluene-4-sulfonic acid;
In
methanol; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1021/jo402618r
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 2-(4-biphenylyl)-5-phenyloxazole; tert.-butylnitrite / acetonitrile / 4 h / 20 °C
2: 5%-palladium/activated carbon; hydrogen / methanol / 4 h / 20 °C / 760.05 Torr
3: tert.-butylnitrite; toluene-4-sulfonic acid / 1,2-dichloro-ethane / 4 h / 0 °C / Inert atmosphere
With
tert.-butylnitrite; 5%-palladium/activated carbon; 2-(4-biphenylyl)-5-phenyloxazole; hydrogen; toluene-4-sulfonic acid;
In
methanol; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1021/jo402618r