Cu₃(O₃SCF₃)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C₆H₆

Base Information

• Chemical Name: Cu₃(O₃SCF₃)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C₆H₆
• CAS No.: 114422-79-6
• Molecular Formula: C₆H₆*C₂₇H₁₂Cu₃F₉O₉S₃
• Molecular Weight: 1016.32
• Mol file: 114422-79-6.mol

Synonyms:

Chemical Property of Cu₃(O₃SCF₃)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C₆H₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu₃(O₃SCF₃)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C₆H₆

There total 2 articles about Cu₃(O₃SCF₃)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C₆H₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

copper(I) trifluoromethanesulfonate benzene (37234-97-2) + tribenzohexahydro[12]annulene (5385-26-2) → Cu3(O3SCF3)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C6H6 (114422-79-6) + Cu(O3SCF3)(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne) (106568-05-2)

Guidance literature:

In butanone; 1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne soln. added to soln. of {Cu2(O3SCF3)2(C6H6)}, mixt. stirred (20 min), small amount of Cu(C6H4C2)3(O3SCF3) formed; filtered, solvent removed (vac.), clear green viscous soln., pptn. by benzene (yellow powder), IR, elem. anal.;

Reference yield:

copper(I) trifluoromethanesulfonate benzene (37234-97-2) + Cu(O3SCF3)(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne) (106568-05-2) → Cu3(O3SCF3)3(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)*C6H6 (114422-79-6)

Guidance literature:

In benzene; prolonged reactn. of {Cu2(O3SCF3)2(C6H6)} with Cu(O3SCF3)(C6H4C2)3 in refluxing benzene;

upstream raw materials:

copper(I) trifluoromethanesulfonate benzene

tribenzohexahydro[12]annulene

Cu(O₃SCF₃)(1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne)

Refernces