trans-[Rh(CO)Cl(4-Ph₂PC₆H₄COOCH₃)2]

Base Information

• Chemical Name: trans-[Rh(CO)Cl(4-Ph₂PC₆H₄COOCH₃)2]
• CAS No.: 625385-17-3
• Molecular Formula: C₄₁H₃₄ClO₅P₂Rh
• Molecular Weight: 807.024
• Mol file: 625385-17-3.mol

Synonyms:

Chemical Property of trans-[Rh(CO)Cl(4-Ph₂PC₆H₄COOCH₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Rh(CO)Cl(4-Ph₂PC₆H₄COOCH₃)2]

There total 1 articles about trans-[Rh(CO)Cl(4-Ph₂PC₆H₄COOCH₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.98%

di(rhodium)tetracarbonyl dichloride + methyl 4-(diphenylphosphino)benzoate (5032-51-9) → trans-[Rh(CO)Cl(4-Ph2PC6H4COOCH3)2] (625385-17-3)

Guidance literature:

In dichloromethane; a soln. of phosphine-compound in CH2Cl2 was added dropwise to a soln. ofcomplex in CH2Cl2 with stirring under N2, the mixt. was stirred at room temp. for about 90 min; evapd., washed with diethyl ether; elem. anal.;

DOI:10.1039/b301674a

upstream raw materials:

methyl 4-(diphenylphosphino)benzoate

Refernces