1-Chlor-cis,trans-2,3-dimethylcyclopropan

Base Information

• Chemical Name: 1-Chlor-cis,trans-2,3-dimethylcyclopropan
• CAS No.: 25271-11-8
• Molecular Formula: C₅H₉Cl
• Molecular Weight: 104.579
• Mol file: 25271-11-8.mol

Synonyms:

Chemical Property of 1-Chlor-cis,trans-2,3-dimethylcyclopropan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Chlor-cis,trans-2,3-dimethylcyclopropan

There total 5 articles about 1-Chlor-cis,trans-2,3-dimethylcyclopropan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-2-Butene (624-64-6) + dichloromethane (75-09-2) → 1-Chlor-cis,trans-2,3-dimethylcyclopropan (25271-11-8,25271-12-9,25271-13-0,53177-35-8)

Guidance literature:

With n-butyllithium; at -35 ℃;

DOI:10.1021/ja01527a057 DOI:10.1021/ja01506a041

Reference yield:

1,1-Dichlor-cis-2,3-dimethyl-cyclopropan (1120-67-8) → 1-Chlor-2,3-cis-dimethylcyclopropan (25271-13-0) + 1-Chlor-cis,cis-dimethylcyclopropan (25271-11-8)

Guidance literature:

With tri-n-butyl-tin hydride; In benzene-d6; at 80 ℃; Product distribution; Mechanism; other gem-dichlorides, (Me₃Si)3SiH as reduction reagent;

DOI:10.1021/ja00102a052

Reference yield:

→ trans-2.3-Dimethyl-cyclopropylchlorid (25271-11-8,25271-12-9,25271-13-0,53177-35-8)

Guidance literature:

Aus trans-Buten-(2) mit Chlordiazomethan in Ae; -20grad, Pyrolyse;

DOI:10.1021/ja00881a034

upstream raw materials:

1,1-Dichlor-cis-2,3-dimethyl-cyclopropan

trans-2-Butene

dichloromethane

Refernces