(+)-lariciresinol

Base Information

• Chemical Name: (+)-lariciresinol
• CAS No.: 105367-81-5
• Molecular Formula: C₂₀H₂₄O₆
• Molecular Weight: 360.407
• Mol file: 105367-81-5.mol

Synonyms:

Chemical Property of (+)-lariciresinol

Chemical Property:

Purity/Quality:

Analysis control,98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-lariciresinol

There total 11 articles about (+)-lariciresinol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(7RS,8R,8'R)-3,3'-dimethoxyligna-4,4',7,9,9'-pentaol → lariciresinol (486-29-3,83327-19-9,105367-81-5,27003-73-2)

Guidance literature:

With boron trifluoride diethyl etherate; In tetrahydrofuran; dichloromethane; at 50 ℃; for 60h;

DOI:10.1039/b202493d

Reference yield:

lariciresinol-4,4'-bis-O-α-L-rhamnoside → lariciresinol (486-29-3,83327-19-9,105367-81-5,27003-73-2)

Guidance literature:

With hesperidinase; In water; at 38 ℃; for 5h;

DOI:10.1016/S0031-9422(00)97835-X

Reference yield:

7S,8R,8'R-(-)-Lariciresinol-4,4'-bis-O-β-D-glucopyranoside (112747-98-5) → D-Glucose (2280-44-6) + lariciresinol (486-29-3,83327-19-9,105367-81-5,27003-73-2)

Guidance literature:

With β-glucosidase; In water; at 37 ℃;

DOI:10.1016/S0031-9422(96)00881-3

upstream raw materials:

(+)-lariciresinol 4'-O-β-D-glucopyranoside

clemastanin B

7S,8R,8'R-(-)-Lariciresinol-4,4'-bis-O-β-D-glucopyranoside

3-methoxy-4-(phenylmethoxy)benzaldehyde

Downstream raw materials:

3-methoxy-4-hydroxybenzoic acid

vanillin

7-acetoxy-1-(4-acetoxy-3-methoxy-phenyl)-2,3-bis-acetoxymethyl-6-methoxy-1,2,3,4-tetrahydro-naphthalene

(4-(3,4-dimethoxybenzyl)-2-(3,4-dimethoxyphenyl)tetrahydrofuran-3-yl)methanol

Refernces

• 1、 El Gamal,Takeya,Itokawa,Halim,Amer,Saad. "Lignan bis-glucosides from Galium sinaicum". . p. 597 - 600. Retrieved 1997.
• 2、 Eklund, Patrik,Sillanpaeae, Reijo,Sjoeholm, Rainer. "Synthetic transformation of hydroxymatairesinol from Norway spruce (picea abies) to 7-hydroxysecoisolariciresinol, (+)-lariciresinol and (+)-cyclolariciresinol". . p. 1906 - 1910. Retrieved 2002.
• 3、 Yamauchi, Satoshi,Sugahara, Takuya,Matsugi, Junko,Someya, Tatsushi,Masuda, Toshiya,Kishida, Taro,Akiyama, Koichi,Maruyama, Masafumi. "Effect of the benzylic structure of lignan on antioxidant activity". . p. 2283 - 2290. Retrieved 2008/03/17.