Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2

Base Information

• Chemical Name: Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2
• CAS No.: 727738-03-6
• Molecular Formula: C₃₁H₂₃B₂ClF₂FeN₆O₆
• Molecular Weight: 726.479
• Mol file: 727738-03-6.mol

Synonyms:

Chemical Property of Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2

There total 1 articles about Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

Fe((difluoroboryl)diphenylglyoximate)(MeCN)2 + N-hydroxy-2-(hydroxyimino)propanimidoyl chloride (4732-59-6) → Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2 (727738-03-6,835619-08-4)

Guidance literature:

With hexamethyldisiloxane; BF₃*O(C₂H₅)2; triethyl amine; In nitromethane; chloroform; to a soln. of complex, Si2(CH3)6 and methylchloroglyoxime in dry CH3NO2 (Ar) a soln. of BF3*O(C2H5)2 and (C2H5)3N in CHCl3 was added dropwise, stirred for 30 min at 70°C, reduced in vol., Si2Me6 and BF3*Et2O in CH3NO were added, heated 20 min; filtered, rotary evapd., pptn. with warm ethanol, the ppt. was washed with ethanol, diethyl ether, hexane, dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2004.08.008

Reference yield: 73.0%

Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2 (727738-03-6,835619-08-4) + thiophenol (108-98-5) → Fe(CH3CNOC(SC6H5)NO)(C6H5CNOCNOC6H5)2(BF)2 (835619-10-8)

Guidance literature:

With triethyl amine; In dichloromethane; a soln. of triethylamine in CH2Cl2 was added dropwise to a stirred soln.of complex and thiophenol n CH2Cl2, the mixt. was stirred for 8 h, left overnight; washed with citric acid, K2CO3 aq. soln., water, dissolved in CH2Cl2, dried over MgSO4, filtered through Silasorb SPH-300, evapd., pptd. with hexane, ppt. was washed with diethyl ether-hexane 1:1, hexane, dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2004.08.008

Reference yield: 60.0%

Fe(methylchloroglyoximato)(α-benzyldioximato)2(BF)2 (727738-03-6,835619-08-4) + Octanethiol (111-88-6) → Fe(CH3CNOC(SC8H17)NO)(C6H5CNOCNOC6H5)2(BF)2 (835619-11-9)

Guidance literature:

With triethyl amine; In N,N-dimethyl-formamide; a soln. of triethylamine in DMF was added dropwise to a stirred soln. ofcomplex and thiol in DMF, the mixt. was stirred for 8 h; pptd. with water, repptd. from DMF-soln. with satd. aq. NaClO4, dissolved in CH2Cl2, filtered through Silasorb SPH-300, evapd. to dryness, washed with a small amount of hexane, dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2004.08.008

upstream raw materials:

N-hydroxy-2-(hydroxyimino)propanimidoyl chloride

Downstream raw materials:

Fe(CH₃CNOC(NHC₂H₄OH)NO)(C₆H₅CNOCNOC₆H₅)2(BF)2

Fe(CH₃CNOC(NHC₅H₁₀NH₂)NO)(C₆H₅CNOCNOC₆H₅)2(BF)2

Fe(CH₃CNOC(SC₆H₅)NO)(C₆H₅CNOCNOC₆H₅)2(BF)2

Fe(CH₃CNOC(SC₈H₁₇)NO)(C₆H₅CNOCNOC₆H₅)2(BF)2

Refernces