[N(o-C₆H₄PPh₂)2]NiBr

Base Information

• Chemical Name: [N(o-C₆H₄PPh₂)2]NiBr
• CAS No.: 881020-83-3
• Molecular Formula: C₃₆H₂₈BrNNiP₂
• Molecular Weight: 675.167
• Mol file: 881020-83-3.mol

Synonyms:

Chemical Property of [N(o-C₆H₄PPh₂)2]NiBr

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N(o-C₆H₄PPh₂)2]NiBr

There total 4 articles about [N(o-C₆H₄PPh₂)2]NiBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

methyl[bis(2-diphenylphosphinophenyl)amide]nickel(II) (579490-58-7) + benzyl bromide (100-39-0) → [N(o-C6H4PPh2)2]NiBr (881020-83-3)

Guidance literature:

In toluene; 100°C, 2 days; volatiles were evapd. in vacuo, residue was recrystd. from benzene;

DOI:10.1021/om050943a

Reference yield:

methyl[bis(2-diphenylphosphinophenyl)amide]nickel(II) (579490-58-7) → [N(o-C6H4PPh2)2]NiBr (881020-83-3)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: acetone

In acetone; toluene;

DOI:10.1021/om050943a

Reference yield:

[N(o-C6H4PPh2)2]Li(THF)2 (579490-52-1) → [N(o-C6H4PPh2)2]NiBr (881020-83-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: acetone

In tetrahydrofuran; acetone;

DOI:10.1021/om050943a

upstream raw materials:

bromobenzene

methyl[bis(2-diphenylphosphinophenyl)amide]nickel(II)

benzyl bromide

[N(o-C₆H₄PPh₂)2]Li(THF)2

Refernces