[RuHCl(H₂)(PCy₃)2]

Base Information

• Chemical Name: [RuHCl(H₂)(PCy₃)2]
• CAS No.: 315675-18-4
• Molecular Formula: C₃₆H₆₉ClP₂Ru
• Molecular Weight: 700.414
• Mol file: 315675-18-4.mol

Synonyms:

Chemical Property of [RuHCl(H₂)(PCy₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuHCl(H₂)(PCy₃)2]

There total 17 articles about [RuHCl(H₂)(PCy₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

RuH2(H2)2(tricyclohexylphosphine)2 (112320-11-3) + dicyclohexylboron chloride (36140-19-9) → RuHCl(H2)(PCy3)2 (315675-18-4,133779-04-1)

Guidance literature:

In hexane; pentane; (under Ar, Schlenk); hexane soln. of ClB(C6H11)2 added to suspn. of Ru-complex in pentane, stirred for 45 min at room temp.; filtered at -60°C, ppt. washed with pentane, dried in vac.; elem anal.;

DOI:10.1021/om700295g

Reference yield: 94.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3) + hydrogen (1333-74-0) + tricyclohexylphosphine (2622-14-2) → RuHCl(H2)(PCy3)2 (315675-18-4,133779-04-1)

Guidance literature:

With triethylamine; In further solvent(s); H2-atmosphere (1.5 atm), sec-butyl alcohol; 80°C (20 h); pptn. on MeOH addn. (room temp.), filtering, washing (MeOH), drying (vac.);

DOI:10.1021/om9705259

Reference yield: 92.0%

dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II) + hydrogen (1333-74-0) + tricyclohexylphosphine (2622-14-2) → RuHCl(H2)(PCy3)2 (315675-18-4,133779-04-1)

Guidance literature:

In isopropyl alcohol; excess of PCy3 was added to i-PrOH soln. of Ru-complex under Ar at room temp., Ar was replaced by H2, suspn. was warmed up to 50 °C, stirred for 40 min; solid was sepd., washed twice with i-PrOH, dried;

DOI:10.1002/1099-0682(200205)2002:5<1076::AID-EJIC1076>3.0.CO;2-4

upstream raw materials:

dichloromethane

hydrogen

tricyclohexylphosphine

dimethylmonochlorosilane

Downstream raw materials:

RuClH(η2-C2H4)(PCy3)2

[RuHCl(Sb(CH₂Ph)3)(PCy₃)2]

RuH2(η2:η2-H2BMes)(PCy3)2

RuHCl(BMes)(PCy₃)2

Refernces

• 1、 -. "METHODS FOR PREPARING RUTHENIUM CARBENE COMPLEXES AND PRECURSORS THERETO". Paragraph 0094. . Retrieved 2014/06/23.
• 2、 Beach, Nicholas J.,Camm, Kenneth D.,Fogg, Deryn E.. "Hydrogenolysis versus methanolysis of first-and second-generation grubbs catalysts: Rates, speciation, and implications for tandem catalysis". . p. 5450 - 5455. Retrieved 2010/12/24.