8,9,17,18,26,27-hexaoxatrispiro[6.2.6¹⁰.2.6¹⁹.2⁷]heptacosane

Base Information

• Chemical Name: 8,9,17,18,26,27-hexaoxatrispiro[6.2.6¹⁰.2.6¹⁹.2⁷]heptacosane
• CAS No.: 31843-92-2
• Molecular Formula: C₂₁H₃₆O₆
• Molecular Weight: 384.513
• Mol file: 31843-92-2.mol

Synonyms:

Chemical Property of 8,9,17,18,26,27-hexaoxatrispiro[6.2.6¹⁰.2.6¹⁹.2⁷]heptacosane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8,9,17,18,26,27-hexaoxatrispiro[6.2.6¹⁰.2.6¹⁹.2⁷]heptacosane

There total 1 articles about 8,9,17,18,26,27-hexaoxatrispiro[6.2.6¹⁰.2.6¹⁹.2⁷]heptacosane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methoxycycloheptene (50438-50-1) → 8,9,17,18,26,27-hexaoxatrispiro[6.2.610.2.619.27]heptacosane (31843-92-2) + 1,1′-bis(hydroperoxy)bis(cycloheptyl)peroxide (51008-02-7) + cycloheptane-1,1-diyl bis-hydroperoxide (352018-71-4)

Guidance literature:

With dihydrogen peroxide; iodine; In acetonitrile; at 18 - 22 ℃; for 6h;

DOI:10.1055/s-0029-1217062

Reference yield: 16.0%

8,9,17,18,26,27-hexaoxatrispiro[6.2.610.2.619.27]heptacosane (31843-92-2) → cyclooctadecane (296-18-4) + oxacycloeicosan-2-one (58296-53-0)

Guidance literature:

In hexane; tert-butyl methyl ether; for 0.116667h; Solvent; Flow reactor; Pyrolysis;

DOI:10.1021/acs.joc.1c00663

upstream raw materials:

1-methoxycycloheptene

Downstream raw materials:

cyclooctadecane

oxacycloeicosan-2-one

Refernces