o-phenylene(dimethylarsine)(dimethylstibine)

Base Information

• Chemical Name: o-phenylene(dimethylarsine)(dimethylstibine)
• CAS No.: 34666-91-6
• Molecular Formula: C₁₀H₁₆AsSb
• Molecular Weight: 332.909
• Mol file: 34666-91-6.mol

Synonyms:

Chemical Property of o-phenylene(dimethylarsine)(dimethylstibine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of o-phenylene(dimethylarsine)(dimethylstibine)

There total 1 articles about o-phenylene(dimethylarsine)(dimethylstibine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-bromophenyl)dimethylarsine (4457-88-9) + sodium (7440-23-5) + dimethylantimony bromide (53234-94-9) → o-phenylene(dimethylarsine)(dimethylstibine) (34666-91-6)

Guidance literature:

With ammonia; In tetrahydrofuran; ammonia; N2-atmosphere; molar ratio Me2SbBr:Na:BrC6H4AsMe2=1:2:1; addn. of Me2SbBr to Na (in liquid NH3, -78°C), stirring (3 h), dropwise addn. toBrC6H4AsMe2 (in THF, -78°C, during 3 h), slow warming to room te mp., refluxing (15 min), cooling; addn. of H2O, sepn. of org. layer, drying, distn.;

DOI:10.1039/DT9790001718

Reference yield: 75.0%

dichlorotris(dimethylphenylphosphine)oxomolybdenum(IV) (30134-06-6) + o-phenylene(dimethylarsine)(dimethylstibine) (34666-91-6) + sodium tetraphenyl borate (143-66-8) → [MoO(Cl)((2-dimethylarsinophenyl)dimethylstibine)2][BPh4] (66059-93-6)

Guidance literature:

In ethanol; N2-atmosphere; stirring and refluxing Mo-complex with excess of ligand for 15 min, pptn. on addn. of NaBPh4 soln.; cooling, filtration, washing (EtOH), drying; elem. anal.;

DOI:10.1039/DT9770002055

Reference yield:

o-phenylene(dimethylarsine)(dimethylstibine) (34666-91-6) → Mn(2+)*2Cl(1-)*(CH3)2SbC6H4As(CH3)2=MnCl2(CH3)2SbC6H4As(CH3)2

Guidance literature:

With manganese(ll) chloride; In tetrahydrofuran;

DOI:10.1039/DT9760001642

upstream raw materials:

(2-bromophenyl)dimethylarsine

sodium

dimethylantimony bromide

Downstream raw materials:

[MoO(Cl)((2-dimethylarsinophenyl)dimethylstibine)2][BPh₄]

(o-dimethylarsinophenyl)dimethylstibine monomethiodide

[MoO(NCS)((2-dimethylarsinophenyl)dimethylstibine)2][BPh₄]