TiCl₂(C₅H₄C(CH₃)(C₂H₅)C₆H₄OCH₃)2

Base Information

• Chemical Name: TiCl₂(C₅H₄C(CH₃)(C₂H₅)C₆H₄OCH₃)2
• CAS No.: 191487-72-6
• Molecular Formula: C₃₂H₃₈Cl₂O₂Ti
• Molecular Weight: 573.439
• Mol file: 191487-72-6.mol

Synonyms:

Chemical Property of TiCl₂(C₅H₄C(CH₃)(C₂H₅)C₆H₄OCH₃)2

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of TiCl₂(C₅H₄C(CH₃)(C₂H₅)C₆H₄OCH₃)2

There total 1 articles about TiCl₂(C₅H₄C(CH₃)(C₂H₅)C₆H₄OCH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.2%

CH3OC6H4C(CH3)(C2H5)Br + 6-methyl-6-ethylfulvene (3141-02-4) + titanium tetrachloride (7550-45-0) → TiCl2(C5H4C(CH3)(C2H5)C6H4OCH3)2 (191487-72-6)

Guidance literature:

With Li; In tetrahydrofuran; diethyl ether; byproducts: LiBr; Ar-atmosphere; dropwise addn. of slight excess of Li-salt of ligand (prepd. from bromo derivative and Li in ether and addn. to fulvene derivative) to TiCl4 (in THF), stirring for 2 h; solvent removal, chromy. (cellulose, CHCl3), addn. of petroleum ether, crystn. (refrigerator), recrystn. (CHCl3/petroleum ether); elem. anal.;

DOI:10.1016/S0022-328X(97)00382-3

upstream raw materials:

6-methyl-6-ethylfulvene

titanium tetrachloride

Refernces