meso-(2R,3S)-2,3-dibutyloxirane

Base Information

• Chemical Name: meso-(2R,3S)-2,3-dibutyloxirane
• CAS No.: 954114-56-8
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.268
• Mol file: 954114-56-8.mol

Synonyms:

Chemical Property of meso-(2R,3S)-2,3-dibutyloxirane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of meso-(2R,3S)-2,3-dibutyloxirane

There total 3 articles about meso-(2R,3S)-2,3-dibutyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

cis-5-decene (7433-78-5) → 6-hydroxydecan-5-one (6540-98-3,27620-76-4) + meso-(2R,3S)-2,3-dibutyloxirane (36229-64-8,954114-56-8) + trans-2,3-dibutyloxirane (2165-61-9)

Guidance literature:

With peracetic acid; ruthenium trichloride; In dichloromethane; water; ethyl acetate; acetonitrile; Ambient temperature;

DOI:10.1021/jo00063a002

Reference yield:

cis-5-decene (7433-78-5) → decane-5,6-diol (54884-84-3) + meso-(2R,3S)-2,3-dibutyloxirane (36229-64-8,954114-56-8)

Guidance literature:

With fluorapatite; urea hydrogen peroxide adduct; Mo₁₂O₄₀P^(3-)*3H⁽¹⁺⁾*3H₃N; at 20 ℃; for 72h;

DOI:10.1016/S0040-4039(02)02033-6

Reference yield:

5-decyne (1942-46-7) → meso-(2R,3S)-2,3-dibutyloxirane (36229-64-8,954114-56-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / H₂ / Lindlar catalyst / quinoline; petroleum ether / 24 h / 20 °C

2: 89 percent / AcOOH; Na₂CO₃ / CH₂Cl₂ / 18 h / 20 °C

With peracetic acid; hydrogen; sodium carbonate; Lindlar's catalyst; In quinoline; dichloromethane; Petroleum ether;

DOI:10.1016/S0040-4039(02)01893-2

upstream raw materials:

cis-5-decene

5-decyne

Downstream raw materials:

decan-5-one

5-decene

cis-5-decene

(E)-5-decene

Refernces

• 1、 Ichihara, Junko,Yamaguchi, Shunro,Nomoto, Takuya,Nakayama, Hirokazu,Iteya, Katsuma,Naitoh, Nozomu,Sasaki, Yoh. "Keggin-type polyacid clusters on apatite: Characteristic catalytic activities in solvent-free oxidation". . p. 8231 - 8234. Retrieved 2007/10/03.