1,1-Dichlorocyclohexane

Base Information

• Chemical Name: 1,1-Dichlorocyclohexane
• CAS No.: 2108-92-1
• Molecular Formula: C6H10 Cl2
• Molecular Weight: 153.051
• Hs Code.: 2903890090
• NSC Number: 9463
• UNII: QXQ6LZL42U
• DSSTox Substance ID: DTXSID20175305
• Nikkaji Number: J80.389H
• Wikidata: Q83045611
• Mol file: 2108-92-1.mol

Synonyms:1,1-DICHLOROCYCLOHEXANE;Cyclohexane, 1,1-dichloro-;2108-92-1;NSC-9463;dichlorocyclohexane;NSC9463;Cyclohexane,1-dichloro-;QXQ6LZL42U;SCHEMBL198516;DTXSID20175305;LQRDJCBZCLUBRY-UHFFFAOYSA-N;NSC 9463

Chemical Property of 1,1-Dichlorocyclohexane

Chemical Property:

• Vapor Pressure: 1.9mmHg at 25°C
• Melting Point: -47°C
• Refractive Index: 1.4803
• Boiling Point: 171°Cat760mmHg
• Flash Point: 66°C
• PSA: 0.00000
• Density: 1.15g/cm³
• LogP: 3.12440
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 152.0159557
• Heavy Atom Count: 8
• Complexity: 70.6

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Halogenated Cyclic Hydrocarbons
• Canonical SMILES: C1CCC(CC1)(Cl)Cl
• Uses: 1,1-Dichlorocyclohexane is used for its absorptions and studied for its dielectric parameters in a styrene polymer matrix.

Technology Process of 1,1-Dichlorocyclohexane

There total 17 articles about 1,1-Dichlorocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

cyclohexanone-oxime (100-64-1) → 1,1-dichlrocyclohexane (2108-92-1)

Guidance literature:

With boron trifluoride diethyl etherate; chlorine; for 8h; Product distribution; other Lewis acids; other oximes;

DOI:10.1021/jo00059a057

Reference yield: 60.0%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 1,1-dichlrocyclohexane (2108-92-1)

Guidance literature:

With tungsten(VI) chloride; In dichloromethane; for 0.166667h; Heating;

DOI:10.1016/S0040-4039(03)01884-7

Reference yield: 42.0%

cyclohexanone-oxime (100-64-1) → chlorofluorocyclohexane (371-89-1) + 1,1-dichlrocyclohexane (2108-92-1)

Guidance literature:

With hydrogen fluoride; chlorine; In diethyl ether; at -10 ℃; for 4h; Product distribution; different solvents, different oxidants;

DOI:10.1016/0022-1139(94)03119-K

upstream raw materials:

1-chlorocyclohexene

cyclohexanone

1,1-difluorocyclohexane

cyclohexanone-oxime

Downstream raw materials:

cyclohexane

1,1-dimethylcyclohexane

cis-1,2-dichloro-cyclohexane

trans-1,2-dichlorocyclohexane

Refernces

• 1、 McLennan. "". . p. 705,706. Retrieved 1966.
• 2、 Werth, Jacob,Berger, Kristen,Uyeda, Christopher. "Cobalt Catalyzed Reductive Spirocyclopropanation Reactions". supporting information. p. 348 - 352. Retrieved 2019/11/28.
• 3、 Tordeux, Marc,Boumizane, Khalid,Wakselman, Claude. "Chlorination of oximes in hydrogen fluoride: formation of gem-dihalogenoalkanes". . p. 207 - 214. Retrieved 2007/10/02.