[AgBF₄*((E,E)-N,N'-bis(pyridylethylene)benzene]

Base Information

• Chemical Name: [AgBF₄*((E,E)-N,N'-bis(pyridylethylene)benzene]
• CAS No.: 517863-58-0
• Molecular Formula: Ag*BF₄*C₂₀H₁₆N₂
• Molecular Weight: 479.033
• Mol file: 517863-58-0.mol

Synonyms:

Chemical Property of [AgBF₄*((E,E)-N,N'-bis(pyridylethylene)benzene]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [AgBF₄*((E,E)-N,N'-bis(pyridylethylene)benzene]

There total 2 articles about [AgBF₄*((E,E)-N,N'-bis(pyridylethylene)benzene] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-((E)-2-[4-[(E)-2-(pyridin-4-yl)vinyl]phenyl]vinyl)pyridine (110144-22-4,3095-81-6) + [(η5-C5H4SiMe3)2Ti(μ-σ,π-CCSiMe3)2]Ag(BF4) → bis(η5-trimethylsilylcyclopentadienyl)bis(trimethylsilylethynyl)-titanium (128247-54-1) + [AgBF4*((E,E)-N,N'-bis(pyridylethylene)benzene] (517863-58-0)

Guidance literature:

In tetrahydrofuran; Ar atm., Ti-complex was stirred with equimolar amounts of dipyridyl-compound in THF at 25°C for 12 h; decanted, the solid was washed with petroleum ether, volatiles were removed in oil-pump vac.;

DOI:10.1016/j.ica.2004.07.054

Reference yield: 32.0%

silver tetrafluoroborate (14104-20-2) + 4-((E)-2-[4-[(E)-2-(pyridin-4-yl)vinyl]phenyl]vinyl)pyridine (110144-22-4,3095-81-6) → [AgBF4*((E,E)-N,N'-bis(pyridylethylene)benzene] (517863-58-0)

Guidance literature:

In dichloromethane; acetonitrile; slow diffusion of 2 equiv. of C6H4(CHCHC5H4N)2 in anhyd. CH2Cl2 and AgBF4 in dry CH3CN (Chem. Commun., 1997, 1675); pptn., filtration, washing with CH2Cl2 and CH3CN; drying in vac. with weak heating, elem. anal.;

DOI:10.1023/A:1021337526344

upstream raw materials:

4-((E)-2-[4-[(E)-2-(pyridin-4-yl)vinyl]phenyl]vinyl)pyridine

silver tetrafluoroborate

Refernces

• 1、 Al-Anber,Stein, Th.,Vatsadze,Lang. "Organometallic π-tweezers incorporating pyrazine- and pyridine-based bridging units". . p. 50 - 56. Retrieved 2008/10/09.