cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene

Base Information

• Chemical Name: cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene
• CAS No.: 102420-54-2
• Molecular Formula: C₂₂H₁₄O₂
• Molecular Weight: 310.352
• Mol file: 102420-54-2.mol

Synonyms:

Chemical Property of cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene

There total 1 articles about cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Indeno[1,2,3-cd]pyrene (193-39-5) → cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene (102420-54-2,99520-57-7)

Guidance literature:

With osmium(VIII) oxide; In pyridine; benzene; for 504h; Yield given; Ambient temperature;

DOI:10.1021/jo00363a005

Reference yield: 75.0%

cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene (102420-54-2,99520-57-7) → 1,2-dihydroindeno<1,2,3-cd>pyrene-1,2-dione (99520-63-5)

Guidance literature:

With manganese(IV) oxide; In benzene; at 60 - 70 ℃; for 1h;

DOI:10.1021/jo00363a005

Reference yield:

cis-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene (102420-54-2,99520-57-7) → (+/-)-trans-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene (102420-56-4,99520-57-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / manganese dioxide / benzene / 1 h / 60 - 70 °C

2: potassium borohydride / aq. ethanol / 3 h / 50 - 60 °C

With manganese(IV) oxide; potassium borohydride; In ethanol; benzene;

DOI:10.1021/jo00363a005

upstream raw materials:

Indeno[1,2,3-cd]pyrene

Downstream raw materials:

1,2-dihydroindeno<1,2,3-cd>pyrene-1,2-dione

1-hydroxyindeno<1,2,3-cd>pyrene

(+/-)-trans-1,2-dihydro-1,2-dihydroxyindeno<1,2,3-cd>pyrene

Refernces