clorine

Base Information

• Chemical Name: clorine
• CAS No.: 14700-96-0
• Molecular Formula: Cl
• Molecular Weight: 35.453
• Mol file: 14700-96-0.mol

Synonyms:

Chemical Property of clorine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of clorine

There total 237 articles about clorine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trichlorothiophosphine (3982-91-0) + water (7732-18-5) → PSCl2(1+) (52826-97-8) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In gas; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube; Kinetics;

DOI:10.1016/j.chemphys.2004.03.033

Reference yield: 95.0%

chlorine azide → nitrene chloride (12190-75-9,10599-90-3) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In neat (no solvent); byproducts: N3, N2; Irradiation (UV/VIS); dominate products by 248-nm photolysis: Cl+N3, also observed NCl+N2; monitored by TOF MS;

DOI:10.1016/j.cplett.2004.04.113

Reference yield: 80.0%

chlorine (7782-50-5) → clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In neat (no solvent); flash photolysis;;

upstream raw materials:

tetrachloromethane

1,1,2,2-tetrachloroethylene

methylene chloride

Trichloroethylene

Downstream raw materials:

Iodine monochloride

hydroxyl

chloride

hydrogenchloride

Refernces

• 1、 Guertler, P.,Calve, J. Le,Raasch, D.. "". . p. 585 - 589. Retrieved 1991.
• 2、 Creasey, J. C.,Lambert, I. R.,Tuckett, R. P.,Codling, K,Frasinski, L. J.,at al.. "Nonradiative decay pathways of electronic states of group IV tetrafluoro and tetrachloro molecular ions studied with synchrotron radiation". . p. 3295 - 3306. Retrieved 1990.
• 3、 Gao, Yide,Alecu,Hsieh,Morgan, Brad P.,Marshall, Paul,Krasnoperov, Lev N.. "Thermochemistry is not a lower bound to the activation energy of endothermic reactions: A kinetic study of the gas-phase reaction of atomi-chlorine with ammonia". . p. 6844 - 6850. Retrieved 2006.
• 4、 Giauque, W. F.,Overstreet, R.. "". . p. 1731 - 1744. Retrieved 1932.
• 5、 Giorgi, Javier B.,Naumkin, Fedor Y.,Polanyi, John C.,Raspopov, Sergei A.,Sze, Newman S. -K. "Surface aligned photochemistry: photodissociation of Cl2 and Cl2...Cl adsorbed on LiF (001)". . p. 9569 - 9581. Retrieved 2000.
• 6、 Kukui,Roggenbuck,Schindler. "Mechanism and Rate Constants for the Reactions of Cl Atoms with HOCl, CH3OCl and tert-C4H9OCl". . p. 281 - 286. Retrieved 1997.
• 7、 Poskrebyshev,Huie,Neta. "The rate and equilibrium constants for the reaction NO3? + Cl- ? NO3- + Cl? in aqueous solutions". . p. 1964 - 1970. Retrieved 2003.
• 8、 Hills, Alan J.,Howard, Carleton J.. "Rate coefficient temperature dependence and branching ratio for the OH + CIO reaction". . p. 4458 - 4465. Retrieved 1984.
• 9、 Brownsword,Kappel,Schmiechen,Upadhyaya,Volpp. "Dynamics of the H+HCl gas-phase reaction: Absolute reactive cross-section for Cl(2P3/2) atom formation". . p. 241 - 246. Retrieved 1998.
• 10、 Berg, P. A.,Sloan, J. J.. "The effect of reagent translational excitation on the dynamics of the reaction H+Cl2 -> HCl(v',J')+Cl". . p. 1075 - 1084. Retrieved 1994.