4-NITROBENZENEAZOMALONONITRILE

Base Information

• Chemical Name: 4-NITROBENZENEAZOMALONONITRILE
• CAS No.: 1080-02-0
• Molecular Formula: C9H11N3O2
• Molecular Weight: 193.205
• Hs Code.: 2928000090
• Mol file: 1080-02-0.mol

Synonyms:[(E)-(4-Nitrophenyl)diazenyl]malononitrile;2-Propanone, (4-nitrophenyl)hydrazone;

Chemical Property of 4-NITROBENZENEAZOMALONONITRILE

Chemical Property:

• PSA: 118.12000
• LogP: 2.61746
• Solubility.: Chloroform, Dichloromethane, Ethyl Acetate

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Nitrobenzeneazomalononitrile ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 4-Nitrobenzeneazomalononitrile (cas# 1080-02-0) is a compound useful in organic synthesis.

Technology Process of 4-NITROBENZENEAZOMALONONITRILE

There total 9 articles about 4-NITROBENZENEAZOMALONONITRILE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

(1-methyl-1-nitroethyl)(p-nitrophenyl)diazene → acetone-(4-nitro-phenylhydrazone) (1080-02-0)

Guidance literature:

With sodium benzylmercaptide; Photolysis;

DOI:10.1039/b103350f

Reference yield:

4-nitrobenzenediazonium tetrafluoroborate (456-27-9) + lithium 2-nitropropane (3958-63-2) → acetone-(4-nitro-phenylhydrazone) (1080-02-0)

Guidance literature:

In dimethyl sulfoxide; Irradiation;

DOI:10.1021/ja00751a043

Reference yield:

4-nitrophenylhydrazone (100-16-3) + acetone (67-64-1) → acetone-(4-nitro-phenylhydrazone) (1080-02-0)

Guidance literature:

With ethanol; acetic acid;

upstream raw materials:

4-nitrophenylhydrazone

acetone

1-(propan-2-ylidene)-2-(4-oxo-thiazolidin-2-ylidene)hydrazine

4-nitrobenzenediazonium tetrafluoroborate

Downstream raw materials:

5,5-dimethyl-2-(4-nitro-phenyl)-[1,2,4]triazolidin-3-one

5,5-Dimethyl-2-(4-nitro-phenyl)-[1,2,4]triazolidine-3-thione

pyruvaldehyde bis-(4-nitro-phenylhydrazone)

C₁₃H₁₅N₃O₄

Refernces

• 1、 Al-Khalil,Bowman,Gaitonde,Marley,Richardson. "Radical-nucleophilic substitution (SRN1) reactions. Part 7. Reactions of aliphatic α-substituted nitro compounds". . p. 1557 - 1565. Retrieved 2007/10/03.
• 2、 Chittenden, Gordon J. F.. "Some aspects of the reaction of glycerol with 2,2-dimethoxypropane". . p. 316 - 323. Retrieved 2007/10/02.