1-METHOXYCYCLOHEXENE

Base Information

• Chemical Name: 1-METHOXYCYCLOHEXENE
• CAS No.: 931-57-7
• Molecular Formula: C7H12O
• Molecular Weight: 112.172
• Hs Code.: 2909209000
• Mol file: 931-57-7.mol

Synonyms:Ether,1-cyclohexen-1-yl methyl (6CI,7CI,8CI);1-Cyclohexen-1-yl methyl ether;1-Methoxy-1-cyclohexene;Cyclohexanone methyl enol ether;2,3,4,5-Tetrahydroanisole;AC1L2DPH;Ether, 1-cyclohexen-1-yl methyl;

Chemical Property of 1-METHOXYCYCLOHEXENE

Chemical Property:

• Appearance/Colour: Colourless oil
• Vapor Pressure: 2.48mmHg at 25°C
• Refractive Index: 1.453
• Boiling Point: 165.3 °C at 760 mmHg
• Flash Point: 44.7 °C
• PSA: 9.23000
• Density: 0.89 g/cm³
• LogP: 2.09070
• Solubility.: Methanol

Purity/Quality:

99% ^*data from raw suppliers

1-METHOXYCYCLOHEXENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1-methoxycyclohexene can be used in organic synthesis and it reacts with hydrochloric acid to form 1-chloro-1-methoxycyclohexane.

Technology Process of 1-METHOXYCYCLOHEXENE

There total 43 articles about 1-METHOXYCYCLOHEXENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

cycloxexanone dimethyl ketal (933-40-4) → 1-methoxy-cyclohex-1-ene (931-57-7)

Guidance literature:

Heating;

DOI:10.1080/00397919808007005

Reference yield: 93.0%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + trimethyl orthoformate (149-73-5) → 1-methoxy-cyclohex-1-ene (931-57-7)

Guidance literature:

With toluene-4-sulfonic acid; for 24h; Ambient temperature;

DOI:10.1039/P19860000829

Reference yield: 61.0%

trimethyl orthoformate (149-73-5) → 1-methoxy-cyclohex-1-ene (931-57-7)

Guidance literature:

With toluene-4-sulfonic acid; In cyclohexanone;

upstream raw materials:

quinoline

cycloxexanone dimethyl ketal

benzoyl chloride

1-methoxy-1,3-cyclohexadiene

Downstream raw materials:

2-methoxycyclohexane

N-(2-Methoxy-cyclohex-2-enylmethyl)-N,N'-dimethyl-ethane-1,2-diamine

N,N'-Dibutyl-N-(2-methoxy-cyclohex-1-enylmethyl)-ethane-1,2-diamine

N,N'-Dibutyl-N-(2-methoxy-cyclohex-2-enylmethyl)-ethane-1,2-diamine

Refernces

• 1、 Szczyglewska, Paulina,Feliczak-Guzik, Agnieszka,Jaroniec, Mietek,Nowak, Izabela. "Catalytic role of metals supported on SBA-16 in hydrodeoxygenation of chemical compounds derived from biomass processing". . p. 9505 - 9517. Retrieved 2021/03/16.
• 2、 Feliczak-Guzik, Agnieszka,Szczyglewska, Paulina,Nowak, Izabela. "The effect of metal (Nb, Ru, Pd, Pt) supported on SBA-16 on the hydrodeoxygenation reaction of phenol". . p. 61 - 67. Retrieved 2018/07/21.