dechloromonilidiol diacetate

Base Information

• Chemical Name: dechloromonilidiol diacetate
• CAS No.: 88557-40-8
• Molecular Formula: C₂₀H₂₆O₆
• Molecular Weight: 362.423
• Mol file: 88557-40-8.mol

Synonyms:

Chemical Property of dechloromonilidiol diacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dechloromonilidiol diacetate

There total 15 articles about dechloromonilidiol diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((4R,5S)-2,2-dimethyl-5-pentyl-1,3-dioxolan-4-yl)methanol (88557-31-7) → dechloromonilidiol diacetate (88557-40-8)

Guidance literature:

Multi-step reaction with 8 steps

1: NaH

2: Amberlyst 15

4: H₂ / Pd/BaSO₄

5: 77.6 percent / oxidizing agent

7: aq. AcOH

8: MnO₂

With manganese(IV) oxide; Amberlyst 15; oxidizing agent; hydrogen; sodium hydride; acetic acid; Pd-BaSO₄;

DOI:10.1271/bbb1961.47.2411

Reference yield:

2,2-Dimethyl-propionic acid (2R,3S)-2,3-dihydroxy-octyl ester (106031-55-4) → dechloromonilidiol diacetate (88557-40-8)

Guidance literature:

Multi-step reaction with 10 steps

2: KOH

3: NaH

4: Amberlyst 15

6: H₂ / Pd/BaSO₄

7: 77.6 percent / oxidizing agent

9: aq. AcOH

10: MnO₂

With manganese(IV) oxide; potassium hydroxide; Amberlyst 15; oxidizing agent; hydrogen; sodium hydride; acetic acid; Pd-BaSO₄;

DOI:10.1271/bbb1961.47.2411

Reference yield:

(2R,3S)-octane-1,2,3-triol (88557-30-6) → dechloromonilidiol diacetate (88557-40-8)

Guidance literature:

Multi-step reaction with 11 steps

3: KOH

4: NaH

5: Amberlyst 15

7: H₂ / Pd/BaSO₄

8: 77.6 percent / oxidizing agent

10: aq. AcOH

11: MnO₂

With manganese(IV) oxide; potassium hydroxide; Amberlyst 15; oxidizing agent; hydrogen; sodium hydride; acetic acid; Pd-BaSO₄;

DOI:10.1271/bbb1961.47.2411

upstream raw materials:

Acetic acid (1R,2S)-2-acetoxy-1-[(E)-2-(3-hydroxy-2-hydroxymethyl-phenyl)-vinyl]-heptyl ester

(3-hydroxy-1,2-phenylene)dimethanol

((4R,5S)-2,2-dimethyl-5-pentyl-1,3-dioxolan-4-yl)methanol

(2R,3S)-octane-1,2,3-triol

Downstream raw materials:

dechloromonilidiol

Refernces