3-(ACRYLOYLOXY)-2-HYDROXYPROPYL METHACRYLATE

Base Information

• Chemical Name: 3-(ACRYLOYLOXY)-2-HYDROXYPROPYL METHACRYLATE
• CAS No.: 1709-71-3
• Molecular Formula: C10H14 O5
• Molecular Weight: 214.218
• Hs Code.: 29161400
• DSSTox Substance ID: DTXSID20407931
• Nikkaji Number: J799.746I
• Mol file: 1709-71-3.mol

Synonyms:2-Propenoicacid, 2-methyl-, 2-hydroxy-3-[(1-oxo-2-propenyl)oxy]propyl ester (9CI);Methacrylic acid, 2,3-dihydroxypropyl ester, 3-acrylate (7CI);1-(Acryloyloxy)-2-hydroxy-3-(methacryloyloxy)propane;1-Methacryloyloxy-3-acryloyloxy-2-propanol;2-Hydroxy-1-acryloxy-3-methacryloxypropane;2-Hydroxy-3-acryloyloxy-1-methacryloyloxypropane; 2-Hydroxy-3-acryloyloxypropylmethacrylate; 2-Hydroxy-3-methacryloyloxypropyl acrylate;3-(Acryloxy)-2-hydroxypropyl methacrylate; 3-Acryloyloxy-2-hydroxypropylmethacrylate; AHPMA; Acrylic acid-glycidyl methacrylate 1:1 adduct; BlemmerGAM; G 201P; Light Ester G 201P; NK Ester 701A

Chemical Property of 3-(ACRYLOYLOXY)-2-HYDROXYPROPYL METHACRYLATE

Chemical Property:

• Vapor Pressure: 0.000101mmHg at 25°C
• Refractive Index: n20/D 1.473(lit.)
• Boiling Point: 301.7°C at 760 mmHg
• PKA: 12.51±0.20(Predicted)
• Flash Point: >230 °F
• PSA: 72.83000
• Density: 1.14 g/mL at 25 °C(lit.)
• LogP: 0.19580
• Storage Temp.: 2-8°C
• Water Solubility.: Insoluble in water
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 214.08412354
• Heavy Atom Count: 15
• Complexity: 269

Purity/Quality:

98% ^*data from raw suppliers

3-(Acryloyloxy)-2-hydroxypropyl methacrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 38-41-43
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(COC(=O)C=C)O

Technology Process of 3-(ACRYLOYLOXY)-2-HYDROXYPROPYL METHACRYLATE

There total 3 articles about 3-(ACRYLOYLOXY)-2-HYDROXYPROPYL METHACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-Epoxypropyl methacrylate (106-91-2,25067-05-4,98104-93-9) + acrylic acid (79-10-7) → 1-(acryloyloxy)-3-(methacryloyloxy)-2-propanol (1709-71-3)

Guidance literature:

2,6-di-tert-butyl-4-methyl-phenol; triethylamine; at 80 ℃; for 48h; Product distribution / selectivity;

Reference yield:

2,3-Epoxypropyl methacrylate (106-91-2,25067-05-4,98104-93-9) + acrylic acid (79-10-7) → glycerol methacrylate acrylate (433937-38-3) + 1-(acryloyloxy)-3-(methacryloyloxy)-2-propanol (1709-71-3)

Guidance literature:

With chromium(lll) acetate; for 80h; Kinetics;

DOI:10.1021/op010112q

Reference yield:

→ 1-(acryloyloxy)-3-(methacryloyloxy)-2-propanol (1709-71-3)

Guidance literature:

Glycidylmethacrylat, Acrylsaeure;

upstream raw materials:

2,3-Epoxypropyl methacrylate

acrylic acid

Downstream raw materials:

2-methylacrylic acid 2-hydroxy-3-[3-(2-methylaziridin-1-yl)propionyloxy]propyl ester

Refernces

• 1、 -. "A dental repair material for methyl acrylate monomer and its preparation method". Page/Page column 4-7. . Retrieved 2019/07/04.
• 2、 -. "Process for preparing hydroxyalkyl(meth) acrylates using Lewis acid catalysts". Page/Page column 4. . Retrieved 2008/06/13.