8,14-cedranoxide

Base Information

• Chemical Name: 8,14-cedranoxide
• CAS No.: 13836-90-3
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.355
• Mol file: 13836-90-3.mol

Synonyms:

Chemical Property of 8,14-cedranoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8,14-cedranoxide

There total 1 articles about 8,14-cedranoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

C15H20O3 (118326-12-8) → (+/-)-8,14-Cedranoxide (13836-90-3,18319-31-8,118354-48-6) + 8-cedren-14-ol (18319-35-2,18319-40-9,118354-44-2)

Guidance literature:

With potassium hydroxide; hydrazine; In ethylene glycol; for 1.5h; Heating;

DOI:10.1016/S0040-4039(00)96939-9

Reference yield:

8,14-cedranoxide (13836-90-3,18319-31-8,118354-48-6) → α-Cedrene (469-61-4,19069-48-8,22567-43-7,35944-22-0,35964-52-4,37720-32-4,38227-40-6,50894-66-1,65354-33-8,65981-45-5)

Guidance literature:

Multi-step reaction with 5 steps

1: BF₃-Et₂O

2: LiAlH₄ / diethyl ether

3: aq. CrO₃ / acetone

4: methanol

5: LiAlH₄ / pyridine

With chromium(VI) oxide; lithium aluminium tetrahydride; boron trifluoride diethyl etherate; In pyridine; methanol; diethyl ether; acetone;

DOI:10.1016/S0040-4020(01)92637-7

Reference yield:

8,14-cedranoxide (13836-90-3,18319-31-8,118354-48-6) → 8-Cedren-14-al-tosylhydrazon

Guidance literature:

Multi-step reaction with 4 steps

1: BF₃-Et₂O

2: LiAlH₄ / diethyl ether

3: aq. CrO₃ / acetone

4: methanol

With chromium(VI) oxide; lithium aluminium tetrahydride; boron trifluoride diethyl etherate; In methanol; diethyl ether; acetone;

DOI:10.1016/S0040-4020(01)92637-7

upstream raw materials:

C₁₅H₂₀O₃

Downstream raw materials:

α-Cedrene

Refernces

• 1、 Shizurif, Yoshikazu,Okuno, Yoshishige,Shigemori, Hideyuki,Yamamura, Shosuke. "EFFICIENT SYNTHESIS OF (+/-)-8,14-CEDRANOXIDE USING ELECTROCHEMICAL METHODS AS A KEY STEP". . p. 6661 - 6664. Retrieved 2007/10/02.