hexyl phenyl ether

Base Information

• Chemical Name: hexyl phenyl ether
• CAS No.: 1132-66-7
• Molecular Formula: C12H18O
• Molecular Weight: 178.274
• Hs Code.: 2909309090
• Mol file: 1132-66-7.mol

Synonyms:hexaoxybenzene;hexyl phenyl ether;Ether,hexyl phenyl;Hexyl-phenyl-aether;Benzene,(hexyloxy);1-phenoxyhexane;(hexyloxy)benzene;Benzene, (hexyloxy)-;

Chemical Property of hexyl phenyl ether

Chemical Property:

• Vapor Pressure: 0.0602mmHg at 25°C
• Melting Point: -19°C
• Refractive Index: 1.4921 (estimate)
• Boiling Point: 240oC at 760 mmHg
• Flash Point: 92.4oC
• PSA: 9.23000
• Density: 0.909g/cm3
• LogP: 3.64570

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of hexyl phenyl ether

There total 57 articles about hexyl phenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

((6-iodohexyl)oxy)benzene (346621-45-2) → 1-phenoxyhexane (1132-66-7)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); hypophosphorous acid; sodium hydrogencarbonate; In ethanol; for 0.5h; Heating;

DOI:10.1246/bcsj.74.225

Reference yield: 97.0%

butyl magnesium bromide (693-04-9) + phenoxyethyl bromide (589-10-6) → 1-phenoxyhexane (1132-66-7)

Guidance literature:

With [((Me)NN₂)NiCl]; In tetrahydrofuran; ISOPROPYLAMIDE; at -35 - 20 ℃; Inert atmosphere;

Reference yield: 95.0%

1-bromo-hexane (111-25-1) + phenol (108-95-2,27073-41-2) → 1-phenoxyhexane (1132-66-7)

Guidance literature:

With sodium hydroxide; Aliquat 336; In water; for 1h; Heating;

DOI:10.1081/SCC-100000172

upstream raw materials:

1-Chlorohexane

sodium phenoxide

1-bromo-hexane

[(2E)-hex-2-en-1-yloxy]benzene

Downstream raw materials:

4-(4-hexyloxy-phenyl)-4-oxo-butyric acid

4-hexyloxy-benzenesulfonic acid amide

1-Iodohexane

4-hexyloxyacetophenone

Refernces

• 1、 Matt, Christof,K?lblin, Frederic,Streuff, Jan. "Reductive C-O, C-N, and C-S Cleavage by a Zirconium Catalyzed Hydrometalation/β-Elimination Approach". supporting information. p. 6983 - 6988. Retrieved 2019/09/09.
• 2、 El-Deeb, Ibrahim Yussif,Tian, Miaomiao,Funakoshi, Tatsuya,Matsubara, Ryosuke,Hayashi, Masahiko. "Conversion of Cyclohexanones to Alkyl Aryl Ethers by Using a Pd/C–Ethylene System". supporting information. p. 409 - 413. Retrieved 2017/01/24.