4-iodoheptane

Base Information

• Chemical Name: 4-iodoheptane
• CAS No.: 31294-93-6
• Molecular Formula: C7H15 I
• Molecular Weight: 226.101
• Mol file: 31294-93-6.mol

Synonyms:4-Iodoheptane

Chemical Property of 4-iodoheptane

Chemical Property:

• Vapor Pressure: 0.976mmHg at 25°C
• Refractive Index: 1.5008 (estimate)
• Boiling Point: 185°C at 760 mmHg
• Flash Point: 65°C
• PSA: 0.00000
• Density: 1.384g/cm³
• LogP: 3.39020

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-iodoheptane

There total 1 articles about 4-iodoheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.1%

n-heptane (142-82-5) → 2-iodoheptane (18589-29-2) + 4-iodoheptane (31294-93-6) + 1-Iodoheptane (4282-40-0) + 3-iodoheptane (31294-92-5)

Guidance literature:

With tert.-butylhydroperoxide; iron(III) acetate; In acetic acid; Title compound not separated from byproducts; Heating;

DOI:10.1039/a703332j

Reference yield: 89.0%

4-iodoheptane (31294-93-6) + 13C-methyldiphenylsilanecarboxylic acid (1346220-47-0) + sodium phenoxide (139-02-6) → [(13)C]-phenyl 2-propylpentanoate

Guidance literature:

With potassium fluoride; propyl cyanide; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; (2-morpholino-N-(quinolin-8-yl)acetamido)nickel(II) chloride; triethylamine; In N,N-dimethyl-formamide; at 20 ℃; for 20h; Inert atmosphere; Sealed tube; Irradiation;

DOI:10.1021/jacs.1c09170

Reference yield: 84.0%

4-iodoheptane (31294-93-6) + diphenylmethylsilanecarboxylic acid (18414-58-9) + sodium phenoxide (139-02-6) → Di-n-propylessigsaeure-phenylester (22179-54-0)

Guidance literature:

With potassium fluoride; propyl cyanide; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; (2-morpholino-N-(quinolin-8-yl)acetamido)nickel(II) chloride; triethylamine; In N,N-dimethyl-formamide; at 20 ℃; for 20h; Inert atmosphere; Sealed tube; Irradiation;

DOI:10.1021/jacs.1c09170

upstream raw materials:

n-heptane

Downstream raw materials:

hept-3-ene

n-heptane

4--buttersaeure

nitrous acid-(1-propyl-butyl ester)

Refernces

• 1、 Liguori, Lucia,Bjorsvik, Hans-Rene,Bravo, Anna,Fontana, Francesca,Minisci, Francesco. "A new direct homolytic iodination reaction of alkanes by perfluoroalkyl iodides". . p. 1501 - 1502. Retrieved 2007/10/03.