Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis-

Base Information

• Chemical Name: Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis-
• CAS No.: 113342-99-7
• Molecular Formula: C11H16N2O5
• Molecular Weight: 256.258
• DSSTox Substance ID: DTXSID40471816
• Wikidata: Q82300480
• Mol file: 113342-99-7.mol

Synonyms:113342-99-7;Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis-;SCHEMBL7466490;SCHEMBL18077348;DTXSID40471816;HTPZJNDSXJBRRR-UHFFFAOYSA-N;2-[(2-hydroxyethyl)-(2-methoxy-4-nitrophenyl)-amino]-ethanol

Chemical Property of Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis-

Chemical Property:

• XLogP3: 0.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 256.10592162
• Heavy Atom Count: 18
• Complexity: 252

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=CC(=C1)[N+](=O)[O-])N(CCO)CCO

Technology Process of Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis-

There total 7 articles about Ethanol, 2,2'-[(2-methoxy-4-nitrophenyl)imino]bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2-[2-hydroxyethyl-(2-methoxyphenyl)amino]ethanol (28005-76-7) → 2-[(2-hydroxyethyl)(2-methoxy-4-nitrophenyl)amino]ethanol (113342-99-7)

Guidance literature:

2-[2-hydroxyethyl-(2-methoxyphenyl)amino]ethanol; With acetic acid; In water; at 20 ℃; for 0.166667h;

With sodium nitrate; In water; at 20 ℃; for 2h;

DOI:10.1039/b922305c

Reference yield: 17.0%

oxirane (75-21-8,99932-75-9) + 2-methoxy-4-nitrophenylamine (97-52-9) → N-(2-hydroxyethyl)-2-methoxy-4-nitroaniline (66095-81-6) + 2-[(2-hydroxyethyl)(2-methoxy-4-nitrophenyl)amino]ethanol (113342-99-7)

Guidance literature:

In water; acetic acid; for 288h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1002/jhet.5570170425

Reference yield: 6.6%

oxirane (75-21-8,99932-75-9) + 3-amino-4-methoxynitrobenzene (99-59-2) → 2-[(2-hydroxyethyl)(2-methoxy-4-nitrophenyl)amino]ethanol (113342-99-7)

Guidance literature:

With sodium hydrogencarbonate; In acetic acid;

upstream raw materials:

oxirane

2-methoxy-4-nitrophenylamine

2-[2-hydroxyethyl-(2-methoxyphenyl)amino]ethanol

1-bromo-2-methoxy-4-nitrobenzene

Downstream raw materials:

2-methoxy-4-nitro-N,N-bis(2-tosylethyl)aniline

N,N-bis(2-Chlorethyl)-4-nitro-o-anisidine

Refernces

• 1、 Su Lim, Chang,Won Kang, Dong,Shun Tian, Yu,Hee Han, Ji,Lim Hwang, Hye,Rae Cho, Bong. "Detection of mercury in fish organs with a two-photon fluorescent probe". supporting information; experimental part. p. 2388 - 2390. Retrieved 2010/08/05.
• 2、 -. "Benzimidazole derivatives". . . Retrieved 2008/06/13.