Carbonylchlorobis(triphenylphosphine)rhodium(I), cis-

Base Information

• Chemical Name: Carbonylchlorobis(triphenylphosphine)rhodium(I), cis-
• CAS No.: 16353-77-8
• Deprecated CAS: 15318-33-9
• Molecular Formula: C₃₇H₃₀ClOP₂Rh
• Molecular Weight: 690.951
• European Community (EC) Number: 237-712-8
• UNII: 84NQM9263V,100LRS254G
• Mol file: 16353-77-8.mol

Synonyms:cis-RhCl(CO)(PPH3)2;UNII-84NQM9263V;Carbonylchlorobis(triphenylphosphine)rhodium(I), cis-;84NQM9263V;13938-94-8;cis-Rhodium carbonyl bis(triphenylphosphine) chloride;Rhodium, carbonylchlorobis(triphenylphosphine)-, cis-;16353-77-8;Rhodium, carbonylchlorobis(triphenylphosphine)-, (sp-4-2)-;trans-Carbonylchlorobis(triphenylphosphine)rhodium(I) cis-form [MI];Carbonylchlorobis(triphenylphosphine)rhodium;Bis(triphenylphosphine)rhodium(I) carbonyl chloride;trans-RhCl(CO)(PPh3)2;CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I)CHLORIDE;100LRS254G;AKOS015916274;AKOS015964110;NSC-168792;J-520008;trans-bis(triphenylphosphine)rhodiumcarbonyl chloride;trans-Carbonylchlorobis(triphenylphosphine)rhodium(I);(SP-4-3)-Carbonylchlorobis(triphenylphosphine)rhodium;TRANS-CARBONYLBIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM(I);TRANS-CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I);TRANS-RHODIUM CARBONYL BIS(TRIPHENYLPHOSPHINE) CHLORIDE;TRANS-CARBONYLCHLOROBIS(TRIPHENYLPHOSP+HINE)RHODIUM(I) [MI];TRANS-CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) [MI]

Chemical Property of Carbonylchlorobis(triphenylphosphine)rhodium(I), cis-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 690.05154
• Heavy Atom Count: 42
• Complexity: 212

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: [C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]

Technology Process of Carbonylchlorobis(triphenylphosphine)rhodium(I), cis-

There total 226 articles about Carbonylchlorobis(triphenylphosphine)rhodium(I), cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) + Wilkinson's catalyst (14694-95-2) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;

DOI:10.1021/om00113a029

Reference yield: 94.0%

Wilkinson's catalyst (14694-95-2) + sorbose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + XYLITOL (87-99-0) + DL-1-deoxy-threitol (4144-94-9,4435-50-1,33818-52-9,41167-49-1,61913-75-5,61913-76-6,122920-28-9,138257-33-7)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 6h;

DOI:10.1021/om00113a029

Reference yield: 92.0%

Wilkinson's catalyst (14694-95-2) + Cinnamoyl chloride (102-92-1,17082-09-6) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

With 1-hexene; In 1,2-dichloro-ethane; byproducts: styryltriphenyltriphosphonium chloride; evacuated and N2 added two times; dichloroethane addn.; evacuated untilboiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; heated 85°C 24 h; decane added; distd. the volatiles; residue recrysd. from dichloroethane;

DOI:10.1021/ja00396a031

upstream raw materials:

Wilkinson's catalyst

fructopyranose

crotonyl chloride

Cinnamoyl chloride

Downstream raw materials:

Wilkinson's catalyst

Rh(CO)(P(C₆H₅)3)2Br₃

Tetramethyl ethylenetetracarboxylate

Rh(I)Br(CO)(PPh₃)2

Refernces

• 1、 Ren, Xinyi,Zheng, Zhiyao,Zhang, Lei,Wang, Zheng,Xia, Chungu,Ding, Kuiling. "Rhodium-Complex-Catalyzed Hydroformylation of Olefins with CO2and Hydrosilane". supporting information. p. 310 - 313. Retrieved 2016/12/30.
• 2、 Coetzee, Jacorien,Eastham, Graham R.,Slawin, Alexandra M. Z.,Cole-Hamilton, David J.. "Mixed anhydride complexes of rhodium(i) and ruthenium(ii)-their synthesis and ligand rearrangements". . p. 3479 - 3491. Retrieved 2014/03/21.