[Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH₂)]

Base Information

• Chemical Name: [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH₂)]
• CAS No.: 460312-19-0
• Molecular Formula: C₁₈H₁₆F₉NOPd
• Molecular Weight: 539.737
• Mol file: 460312-19-0.mol

Synonyms:

Chemical Property of [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH₂)]

There total 1 articles about [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

di-μ-chlorobis-[[2-(dimethylamino)methyl]phenyl-C,N]dipalladium(II) + water (7732-18-5) + 2,4,6-tris(trilfuoromethyl)phenyllithium (444-40-6) → [Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH2)] (460312-19-0)

Guidance literature:

In diethyl ether; under N2, mixt. was stirred for 24 h at room temp., two drops of water was added; volatiles were removed, residue was extd. with CH2Cl2, filtered, hexane was added, soln. was concd., cooled to -20°C, ppt. was decanted, washed with hexane, dried in vac.; elem. anal.;

DOI:10.1021/om020198r

Reference yield: 84.0%

[Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH2)] (460312-19-0) + carbon monoxide (201230-82-2) → [Pd(N,N-dimethylbenzylamine)(1,3,5-C6H2(CF3)3)(CO)] (460312-21-4)

Guidance literature:

In toluene; under N2, CO was bubbled through a soln. which was stirred at room temp.for 30 min; solvent was removed, ppt. was washed with hexane, recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/om020198r

Reference yield: 74.0%

[Pd(dimethylbenzylamine)(2,4,6-tris(trifluoromethyl)phenyl)(OH2)] (460312-19-0) + tert-butylisonitrile (119072-55-8,7188-38-7) → [Pd(N,N-dimethylbenzylamine)(1,3,5-C6H2(CF3)3)(CN-t-Bu)] (460312-20-3)

Guidance literature:

In toluene; under N2, mixt. was stirred at room temp. for 1 h; solvent was removed, hexane was added, volatiles were removed, this was repeated twice, ppt. was recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/om020198r

upstream raw materials:

water

2,4,6-tris(trilfuoromethyl)phenyllithium

Downstream raw materials:

[Pd(N,N-dimethylbenzylamine)(1,3,5-C₆H₂(CF₃)3)(CN-t-Bu)]

[Pd(N,N-dimethylbenzylamine)(1,3,5-C₆H₂(CF₃)3)(2,6-lutidine)]

[Pd(N,N-dimethylbenzylamine)(1,3,5-C₆H₂(CF₃)3)(CO)]

[Pd(N,N-dimethylbenzylamine)(1,3,5-C₆H₂(CF₃)3)(PPh₃)]

Refernces