[1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III)

Base Information

• Chemical Name: [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III)
• CAS No.: 250374-47-1
• Molecular Formula: C₂₃H₂₇BF₂O₄
• Molecular Weight: 416.273
• Mol file: 250374-47-1.mol

Synonyms:

Chemical Property of [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III)

There total 4 articles about [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + [Pd(1,3-di(4-n-butoxyphenyl)propane-1,3-dionato)2] (816453-85-7) → [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III) (250374-47-1)

Guidance literature:

In dichloromethane; excess of B compd. added to soln. of Pd compd., refluxed for 3 h; allowed to cool to room temp., filtered, concd. in vac., pptd. with hexane, filtered, dried in vac.;

DOI:10.1016/j.inoche.2004.06.011

Reference yield: 50.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + 1,3-Di-(p-n-butoxyphenyl)propane-1,3-dione (107265-32-7) → [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III) (250374-47-1)

Guidance literature:

With NaH; In dichloromethane; excess of B compd. added to soln. of Na compd. (prepared in situ from diketone and slight excess of 60% NaH), refluxed for 24 h; allowed to cool to room temp., filtered;

DOI:10.1016/j.inoche.2004.06.011

Reference yield: 50.0%

sodium tetrafluoroborate (13755-29-8) + 1,3-Di-(p-n-butoxyphenyl)propane-1,3-dione (107265-32-7) → [1,3-di(4-n-butoxyphenyl)propane-1,3-dionato]difluoroboron(III) (250374-47-1)

Guidance literature:

In methanol; dichloromethane; excess of B compd. added to soln. of org. compd., refluxed for 24 h; allowed to cool to room temp., filtered;

DOI:10.1016/j.inoche.2004.06.011

upstream raw materials:

tetrafluoroboric acid diethyl ether

[Pd(1,3-di(4-n-butoxyphenyl)propane-1,3-dionato)2]

3,5-bis(4-butoxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole

1,3-Di-(p-n-butoxyphenyl)propane-1,3-dione

Refernces