Tritylallyl ether

Base Information

• Chemical Name: Tritylallyl ether
• CAS No.: 1235-22-9
• Molecular Formula: C22H20O
• Molecular Weight: 300.4
• Hs Code.: 2909309090
• Mol file: 1235-22-9.mol

Synonyms:allyl-trityl ether;Allyl-trityl-aether;α-Allyloxy-triphenylmethan;

Chemical Property of Tritylallyl ether

Chemical Property:

• PSA: 9.23000
• LogP: 5.18110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tritylallyl ether

There total 7 articles about Tritylallyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

trityl chloride (76-83-5) + allyl alcohol (107-18-6) → allyl trityl ether (1235-22-9)

Guidance literature:

With pyridine;

DOI:10.1016/S0957-4166(99)00390-0

Reference yield: 88.0%

2-pyridyl trityl ether (87839-55-2) + allyl alcohol (107-18-6) → allyl trityl ether (1235-22-9)

Guidance literature:

In 1,2-dichloro-ethane; at 80 ℃; for 96h;

Reference yield: 82.0%

1-(Triphenylmethyl)-4(1H)-pyridon (87839-57-4) + allyl alcohol (107-18-6) → allyl trityl ether (1235-22-9)

Guidance literature:

In 1,2-dichloro-ethane; at 80 ℃; for 96h;

upstream raw materials:

triphenylmethyl alcohol

allyl alcohol

1-(Triphenylmethyl)-4(1H)-pyridon

2-pyridyl trityl ether

Downstream raw materials:

<(S^*/R^*)-2-Chloro-1-(trityloxymethyl)ethyl>-(2,3:5,6-di-O-isopropyliden-β-D-mannofuranosyl)-disulfid

<(S^*/R^*)-2-Bromo-1-(trityloxymethyl)ethyl>-(2,3:5,6-di-O-isopropyliden-β-D-mannofuranosyl)-disulfid

α-trityloxyacetaldehyde

(2S)-1-triphenylmethoxy-4-pentene-2-ol

Refernces

• 1、 Li, Jiaqiang,Zhang, Xiaohui,Shen, Hang,Liu, Qing,Pan, Jing,Hu, Wen,Xiong, Yan,Chen, Changguo. "Boron Trifluoride?Diethyl Ether-Catalyzed Etherification of Alcohols: A Metal-Free Pathway to Diphenylmethyl Ethers". supporting information. p. 3115 - 3120. Retrieved 2015/11/03.
• 2、 Iranpoor, Nasser,Mothaghineghad, Enayatholah. "Cerium(IV), as a selective and efficient catalyst for alcoholyses of allylic and tertiary benzylic alcohols". . p. 1859 - 1870. Retrieved 2007/10/02.