[(C₅H₅)(CO)(P(OCH₃)3)Fe(N₄CC₆H₄CN)Fe(CO)(P(OCH₃)3)(C₅H₅)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(N₄CC₆H₄CN)(Fe(CO)(P(OCH₃)3)(C₅H₅))2]O₃SCF₃

Base Information

• Chemical Name: [(C₅H₅)(CO)(P(OCH₃)3)Fe(N₄CC₆H₄CN)Fe(CO)(P(OCH₃)3)(C₅H₅)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(N₄CC₆H₄CN)(Fe(CO)(P(OCH₃)3)(C₅H₅))2]O₃SCF₃
• CAS No.: 852834-71-0
• Molecular Formula: CF₃O₃S*C₂₆H₃₂Fe₂N₅O₈P₂
• Molecular Weight: 865.281
• Mol file: 852834-71-0.mol

Synonyms:

Chemical Property of [(C₅H₅)(CO)(P(OCH₃)3)Fe(N₄CC₆H₄CN)Fe(CO)(P(OCH₃)3)(C₅H₅)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(N₄CC₆H₄CN)(Fe(CO)(P(OCH₃)3)(C₅H₅))2]O₃SCF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₅H₅)(CO)(P(OCH₃)3)Fe(N₄CC₆H₄CN)Fe(CO)(P(OCH₃)3)(C₅H₅)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(N₄CC₆H₄CN)(Fe(CO)(P(OCH₃)3)(C₅H₅))2]O₃SCF₃

There total 2 articles about [(C₅H₅)(CO)(P(OCH₃)3)Fe(N₄CC₆H₄CN)Fe(CO)(P(OCH₃)3)(C₅H₅)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(N₄CC₆H₄CN)(Fe(CO)(P(OCH₃)3)(C₅H₅))2]O₃SCF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

sodium azide + [((C5H5)(CO)(P(OCH3)3)Fe)2(NCC6H4CN)](2+)*2O3SCF3(1-)=[((C5H5)(CO)(P(OCH3)3)Fe)2(NCC6H4CN)](O3SCF3)2 → rac-(cyclopentadienyl)Fe(carbonyl)(P(OCH3)3)(N4CC6H4CN) (463945-94-0) + [(C5H5)(CO)(P(OCH3)3)Fe(N4CC6H4CN)Fe(CO)(P(OCH3)3)(C5H5)](1+)*O3SCF3(1-)=[(N4CC6H4CN)(Fe(CO)(P(OCH3)3)(C5H5))2]O3SCF3 (852834-71-0)

Guidance literature:

In acetonitrile; (Ar); Schlenk technique; NaN3 was added to stirred soln. of Fe complex in MeCN at room temp.; suspn. was stirred at room temp. for 12 h; IR monitoring; filtered through Celite; evapd.; chromd. (alumina, CH2Cl2, CH2Cl2/CH3CN, 1/1); elem. anal.;

DOI:10.1016/j.jorganchem.2004.12.007

Reference yield:

5-(4-cyanophenyl)tetrazole (14389-10-7) + [(C5H5)(CO)(P(OCH3)3)Fe(C4H8O)](1+)*O3SCF3(1-)=[(C5H5)(CO)(P(OCH3)3)Fe(C4H8O)](O3SCF3) (463945-73-5) → rac-(cyclopentadienyl)Fe(carbonyl)(P(OCH3)3)(N4CC6H4CN) (463945-94-0) + [(C5H5)(CO)(P(OCH3)3)Fe(N4CC6H4CN)Fe(CO)(P(OCH3)3)(C5H5)](1+)*O3SCF3(1-)=[(N4CC6H4CN)(Fe(CO)(P(OCH3)3)(C5H5))2]O3SCF3 (852834-71-0)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; (Ar); Schlenk technique; suspn. of tetrazole in DMF was treated with Et3N; soln. was added to soln. of Fe complex in DMF; mixt. was reacted for 4 h; IR monitoring; evapd.; dissolved in CH2Cl2; filtered; chromd. (alumina, CH2Cl2/CH3CN);

DOI:10.1016/j.jorganchem.2004.12.007

upstream raw materials:

5-(4-cyanophenyl)tetrazole

[(C₅H₅)(CO)(P(OCH₃)3)Fe(C₄H₈O)]⁽¹⁺⁾*O₃SCF₃^(1-)=[(C₅H₅)(CO)(P(OCH₃)3)Fe(C₄H₈O)](O₃SCF₃)

Refernces