di(-)-isopulegyl fumarate

Base Information

• Chemical Name: di(-)-isopulegyl fumarate
• CAS No.: 593279-34-6
• Molecular Formula: C₂₄H₃₆O₄
• Molecular Weight: 388.547
• Mol file: 593279-34-6.mol

Synonyms:

Chemical Property of di(-)-isopulegyl fumarate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di(-)-isopulegyl fumarate

There total 1 articles about di(-)-isopulegyl fumarate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

fumaryl dichloride (627-63-4) + isopulegol (7786-67-6,18674-65-2,20549-46-6,21290-09-5,29141-10-4,50373-36-9,59905-53-2,59905-54-3,96612-21-4,104870-56-6,121468-66-4,122517-60-6,122517-61-7,144541-38-8,89-79-2) → di(-)-isopulegyl fumarate (593279-34-6)

Guidance literature:

In toluene; for 20h; Heating;

DOI:10.1016/S0957-4166(03)00172-1

Reference yield:

anthracene (120-12-7) + di(-)-isopulegyl fumarate (593279-34-6) → (11S,12S)-diisopulegyloxycarbonyl-9,10-dihydro-9,10-ethanoanthracene + C38H46O4

Guidance literature:

di(-)-isopulegyl fumarate; With aluminium trichloride; In toluene; at 25 ℃; for 1.5h;

anthracene; In toluene; at 25 ℃; for 48h; Title compound not separated from byproducts;

DOI:10.1016/S0957-4166(03)00172-1

Reference yield:

anthracene (120-12-7) + di(-)-isopulegyl fumarate (593279-34-6) → (S,S)-11,12-bis(hydroxymethyl)-9,10-dihydro-9,10-ethanoanthracene (5445-55-6,26495-88-5,33216-02-3,41063-84-7,41204-44-8,71991-70-3) + (R,R)-11,12-bis(hydroxymethyl)-9,10-dihydro-9,10-ethanoanthracene (5445-55-6,26495-88-5,33216-02-3,41063-84-7,41204-44-8,71991-70-3)

Guidance literature:

di(-)-isopulegyl fumarate; With aluminium trichloride; In toluene; at 25 ℃; for 1.5h;

anthracene; In toluene; at 25 ℃; for 48h;

With lithium aluminium tetrahydride; In diethyl ether; for 3h; Title compound not separated from byproducts; Heating;

DOI:10.1016/S0957-4166(03)00172-1

upstream raw materials:

fumaryl dichloride

isopulegol

Downstream raw materials:

(S,S)-11,12-bis(hydroxymethyl)-9,10-dihydro-9,10-ethanoanthracene

(R,R)-11,12-bis(hydroxymethyl)-9,10-dihydro-9,10-ethanoanthracene

Refernces