(C₆F₅)2Co(CO)3

Base Information

• Chemical Name: (C₆F₅)2Co(CO)3
• CAS No.: 89377-44-6
• Molecular Formula: C₁₅CoF₁₀O₃
• Molecular Weight: 477.14
• Mol file: 89377-44-6.mol

Synonyms:

Chemical Property of (C₆F₅)2Co(CO)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆F₅)2Co(CO)3

There total 2 articles about (C₆F₅)2Co(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II) (60528-58-7) + carbon monoxide (201230-82-2) → tricarbonyl bis(pentafluorophenyl)cobalt (89377-44-6)

Guidance literature:

In toluene; dissolving in dry, deoxygenated toluene; cooling to 0°C, addn. of 1 atm CO;; crystn. after 1.5 h/0°C; decanting liquid, drying under vac. at 0°C; CO-content is determined by warming to 30°C in toluene under vac. (conversion into educt); growing impurities of C6F5Co(CO)4 are detected on prolonged IR analysis;;

DOI:10.1016/0022-328X(83)87184-8

Reference yield:

Co(C6F5)2(C4H8O2)2 → C6F5Co(CO)4 + (C6F5)2Co(CO)3 (89377-44-6)

Guidance literature:

With CO; In hexane; Co bubbled through suspn. of complex for 2 h at room temp.; solid filtered off, washed with hexane, dried in vac., soln. filtered, evapd., sublimed under reduced pressure at 20-25 °C;

DOI:10.1016/S0022-328X(00)81479-5

upstream raw materials:

(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)

carbon monoxide

Refernces

• 1、 Royo, P.,Vazquez, A.. "CARBONYL-ORGANOCOBALT(I) AND -(II) COMPLEXES". . p. 223 - 228. Retrieved 2007/10/02.