ReCl₃(P(CH₂CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: ReCl₃(P(CH₂CH₂P(C₆H₅)2)3)
• CAS No.: 33849-29-5
• Molecular Formula: C₄₂H₄₂Cl₃P₄Re
• Molecular Weight: 963.257
• Mol file: 33849-29-5.mol

Synonyms:

Chemical Property of ReCl₃(P(CH₂CH₂P(C₆H₅)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of ReCl₃(P(CH₂CH₂P(C₆H₅)2)3)

There total 1 articles about ReCl₃(P(CH₂CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

ReCl3(PMePh2)3 (23136-99-4,80656-01-5) + tris(2-diphenylphosphinoethyl)phosphine (23582-03-8) → ReCl3(P(CH2CH2P(C6H5)2)3) (33849-29-5)

Guidance literature:

In neat (no solvent); heating a mixt. of Re-complex and tetraphos-2 at ca. 200°C for 2 h under N2 or Ar; cooling to room temp., addn. of EtOH, stirring overnight , filtn., washing with EtOH, drying in vacuo overnight;

DOI:10.1016/0022-328X(93)83286-5

Reference yield: 65.0%

ReCl3(P(CH2CH2P(C6H5)2)3) (33849-29-5) → ReH3(P(CH2CH2P(C6H5)2)3) (152248-99-2)

Guidance literature:

With NaBH₄; In benzene; suspending Re-complex in benzene and EtOH under N2 or Ar addn. of NaBH4, refluxing for 2 h, pptn.; filtn., washing with benzene, removal of solvents from filtn. and washing, addn. of EtOH, pptn., filtn., washing with EtOH, drying in vacuo, elem. anal.;

DOI:10.1016/0022-328X(93)83286-5

upstream raw materials:

ReCl₃(PMePh₂)₃

tris(2-diphenylphosphinoethyl)phosphine

Downstream raw materials:

ReH₃(P(CH₂CH₂P(C₆H₅)2)3)

Refernces