Fe(CO)3((C₆H₅)2PCH₂C(O)C₆H₅)2

Base Information

• Chemical Name: Fe(CO)3((C₆H₅)2PCH₂C(O)C₆H₅)2
• CAS No.: 143267-48-5
• Molecular Formula: C₄₃H₃₄FeO₅P₂
• Molecular Weight: 748.534
• Mol file: 143267-48-5.mol

Synonyms:

Chemical Property of Fe(CO)3((C₆H₅)2PCH₂C(O)C₆H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(CO)3((C₆H₅)2PCH₂C(O)C₆H₅)2

There total 2 articles about Fe(CO)3((C₆H₅)2PCH₂C(O)C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + (diphenylphosphino)acetophenone (82363-89-1) → Fe(CO)3((C6H5)2PCH2C(O)C6H5)2 (143267-48-5)

Guidance literature:

With Na(BH₄); In butan-1-ol; reaction in refluxing 1-butanol;;

Reference yield:

{Et3NH}{HFe3(CO)11} + (diphenylphosphino)acetophenone (82363-89-1) → Fe(CO)3((C6H5)2PCH2C(O)C6H5)2 (143267-48-5)

Guidance literature:

In butan-1-ol; P-comp. was added to an n-BuOH soln. of Fe-comp. After 2 h of reflux, the mixture was cooled to room temp.; A yellow solid precipitated. It was filtered off, washed with pentane, extracted with CH2Cl2. The soln. was concentrated, and addition of methanol afforded the microcrystalline Fe-complex. Elem. anal.;

Reference yield:

Fe(CO)3((C6H5)2PCH2C(O)C6H5)2 (143267-48-5) → cis-Fe{Ph2PCHC(O)Ph}2(CO)2

Guidance literature:

With HBF₄; In tetrahydrofuran; The reaction with excess HBF4 at room temp. give a yellow, cationic complex.; Chromatography through silica gel column.;

upstream raw materials:

iron pentacarbonyl

(diphenylphosphino)acetophenone

Refernces